chloro-trimethyl-silane; sodium iodide in acetonitrile
T=25°C; 3 h;
参考文献
Tsuboi, Sadao; Wu, Xue Han; Maeda, Seiji; Ono, Shinichiro; Kuroda, Akihisha; et al.
Bulletin of the Chemical Society of Japan, 1987 , vol. 60, # 3 p. 1103 - 1108
1: 88 percent / pyridine / 3 h / 60 - 80 °C
2: 52.1 percent / O3
3: 79 percent
4: 98 percent / propionic acid / 24 h / Heating
5: 91 percent / Al2O3 / benzene / 11 h / Heating
6: 60 percent / LiAl(t-BuO)H3 / tetrahydrofuran / 3 h / -50 °C
7: 93 percent / activated MnO2 / petroleum ether / 2 h / 25 °C
8: 1.) Mg / 1.) THF, 2 h, 2.) THF, -15 deg C, 2 h
9: 54 percent / Me3SiCl, NaI / acetonitrile / 3 h / 25 °C
View Scheme
参考文献
Tsuboi, Sadao; Wu, Xue Han; Maeda, Seiji; Ono, Shinichiro; Kuroda, Akihisha; et al.
Bulletin of the Chemical Society of Japan, 1987 , vol. 60, # 3 p. 1103 - 1108
1: 1.) Mg / 1.) THF, 2 h, 2.) THF, -15 deg C, 2 h
2: 54 percent / Me3SiCl, NaI / acetonitrile / 3 h / 25 °C
View Scheme
参考文献
Tsuboi, Sadao; Wu, Xue Han; Maeda, Seiji; Ono, Shinichiro; Kuroda, Akihisha; et al.
Bulletin of the Chemical Society of Japan, 1987 , vol. 60, # 3 p. 1103 - 1108
1: 60 percent / LiAl(t-BuO)H3 / tetrahydrofuran / 3 h / -50 °C
2: 93 percent / activated MnO2 / petroleum ether / 2 h / 25 °C
3: 1.) Mg / 1.) THF, 2 h, 2.) THF, -15 deg C, 2 h
4: 54 percent / Me3SiCl, NaI / acetonitrile / 3 h / 25 °C
View Scheme
参考文献
Tsuboi, Sadao; Wu, Xue Han; Maeda, Seiji; Ono, Shinichiro; Kuroda, Akihisha; et al.
Bulletin of the Chemical Society of Japan, 1987 , vol. 60, # 3 p. 1103 - 1108
1: 98 percent / propionic acid / 24 h / Heating
2: 91 percent / Al2O3 / benzene / 11 h / Heating
3: 60 percent / LiAl(t-BuO)H3 / tetrahydrofuran / 3 h / -50 °C
4: 93 percent / activated MnO2 / petroleum ether / 2 h / 25 °C
5: 1.) Mg / 1.) THF, 2 h, 2.) THF, -15 deg C, 2 h
6: 54 percent / Me3SiCl, NaI / acetonitrile / 3 h / 25 °C
View Scheme
参考文献
Tsuboi, Sadao; Wu, Xue Han; Maeda, Seiji; Ono, Shinichiro; Kuroda, Akihisha; et al.
Bulletin of the Chemical Society of Japan, 1987 , vol. 60, # 3 p. 1103 - 1108
1: 1.) Mg / 1.) THF, 2 h, 2.) THF, -15 deg C, 2 h
2: 54 percent / Me3SiCl, NaI / acetonitrile / 3 h / 25 °C
View Scheme
参考文献
Tsuboi, Sadao; Wu, Xue Han; Maeda, Seiji; Ono, Shinichiro; Kuroda, Akihisha; et al.
Bulletin of the Chemical Society of Japan, 1987 , vol. 60, # 3 p. 1103 - 1108
1: 93 percent / activated MnO2 / petroleum ether / 2 h / 25 °C
2: 1.) Mg / 1.) THF, 2 h, 2.) THF, -15 deg C, 2 h
3: 54 percent / Me3SiCl, NaI / acetonitrile / 3 h / 25 °C
View Scheme
参考文献
Tsuboi, Sadao; Wu, Xue Han; Maeda, Seiji; Ono, Shinichiro; Kuroda, Akihisha; et al.
Bulletin of the Chemical Society of Japan, 1987 , vol. 60, # 3 p. 1103 - 1108
1: 91 percent / Al2O3 / benzene / 11 h / Heating
2: 60 percent / LiAl(t-BuO)H3 / tetrahydrofuran / 3 h / -50 °C
3: 93 percent / activated MnO2 / petroleum ether / 2 h / 25 °C
4: 1.) Mg / 1.) THF, 2 h, 2.) THF, -15 deg C, 2 h
5: 54 percent / Me3SiCl, NaI / acetonitrile / 3 h / 25 °C
View Scheme
参考文献
Tsuboi, Sadao; Wu, Xue Han; Maeda, Seiji; Ono, Shinichiro; Kuroda, Akihisha; et al.
Bulletin of the Chemical Society of Japan, 1987 , vol. 60, # 3 p. 1103 - 1108
