反应条件
in hexane Mo2(O-i-Pr)6 was dissolved in a min. amt. of hexane under N2. At room temp., acetyl bromide was added and the mixt. was shaken vigorously. The color changed from yellow to burgundy, and enough heat was evolved that the flask was very hot to touch.; The flask was then allowed to stand to cool to room temp. undisturbed for several h. After 2 h crystals were present. The soln. was then cooled to -15°C. After 1 d crystals were collected by filtration and dried in vacuo. Elem.anal.;
参考文献
Chisholm, Malcolm H.; Clark, David L.; Errington, R. John; Folting, Kirsten; Huffman, John C.
Inorganic Chemistry, 1988 , vol. 27, p. 2071 - 2084
