2-氯-1-(2,5-二甲基苯基)-乙酮合成路线 （共 16 条）
参考文献
Collet
Bulletin de la Societe Chimique de France, 1897 , vol. <3> 17, p. 508
反应条件
1: α-chloro-2',5'-dimethylacetophenone; 3-hydroxy-2,2-dimethylpropanol With toluene-4-sulfonic acid in xylene 7 h; Heating / reflux; 2: ethylene glycol With sodium hydroxide; water T=190 - 195°C; 6 h; Heating / reflux; 3: With hydrogenchloride in water; ethylene glycol pH=1; Product distribution / selectivity;
参考文献
BAYER CROPSCIENCE AKTIENGESELLSCHAFT
Patent: WO2005/75401 A1, 2005 ;
Location in patent: Page/Page column 14 ;
反应条件
1: α-chloro-2',5'-dimethylacetophenone; 3-hydroxy-2,2-dimethylpropanol With toluene-4-sulfonic acid in xylene 6 h; Heating / reflux; 2: sodium acetate in ethylene glycol P=112.511 - 127.513 Torr; Heating / reflux; 3: With hydrogenchloride; sodium hydroxide; water Product distribution / selectivity; more than 3 stages;
参考文献
BAYER CROPSCIENCE AKTIENGESELLSCHAFT
Patent: WO2005/75401 A1, 2005 ;
Location in patent: Page/Page column 13 ;
反应条件
1: α-chloro-2',5'-dimethylacetophenone; 3-hydroxy-2,2-dimethylpropanol With toluene-4-sulfonic acid in xylene 6 h; Heating / reflux; 2: potassium acetate in ethylene glycol T=183 - 189°C; 5 h; 3: With hydrogenchloride; sodium hydroxide; water Product distribution / selectivity; more than 3 stages;
参考文献
BAYER CROPSCIENCE AKTIENGESELLSCHAFT
Patent: WO2005/75401 A1, 2005 ;
Location in patent: Page/Page column 12 ;
反应条件
in benzene UV-irradiation; Kinetics;
参考文献
Pelliccioli; Klan; Zabadal; Wirz
Journal of the American Chemical Society, 2001 , vol. 123, # 32 p. 7931 - 7932
反应条件
sodium hydrogencarbonate T=20°C; 20 h; UV-irradiation;
参考文献
Plistil, Lukas; Solomek, Tomas; Wirz, Jakob; Heger, Dominik; Klan, Petr
Journal of Organic Chemistry, 2006 , vol. 71, # 21 p. 8050 - 8058
反应条件
in methanol 12 h; Irradiation;
参考文献
Journal of Organic Chemistry, , vol. 50, # 26 p. 5612 - 5615
反应条件
sodium hydrogencarbonate T=20°C; 20 h; UV-irradiation;
参考文献
Plistil, Lukas; Solomek, Tomas; Wirz, Jakob; Heger, Dominik; Klan, Petr
Journal of Organic Chemistry, 2006 , vol. 71, # 21 p. 8050 - 8058
反应条件
12 h; Irradiationother α-chloro phenones; Product distributionMechanismQuantum yield;
参考文献
Journal of Organic Chemistry, , vol. 50, # 26 p. 5612 - 5615
反应条件
in benzene 12 h; Irradiation; Quantum yield;
参考文献
Bergmark, William R.; Barnes, Curtis; Clark, Jeffrey; Paparian, Seth; Marynowski, Susan
Journal of Organic Chemistry, 1985 , vol. 50, # 26 p. 5612 - 5615
