water in acetonitrile
T=25°C; solvolytic reaction; role of nucleophilic and other solvation effects; ΔH(activ.), ΔS(activ.); further temp. 39.9 deg C; Rate constantThermodynamic data;
参考文献
Bentley, T. William; Llewellyn, Gareth; Ryu, Zoon Ha
Journal of Organic Chemistry, 1998 , vol. 63, # 14 p. 4654 - 4659
Fleming, Ian; Newton, Trevor W.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , p. 119 - 124
fluorine
T=-30 - 10°C; steady-state flow process; the hydrocarbon vapor is condensed onto a NaF preaerosol and then subjected to attack by elemental F in He in the dark; MechanismProduct distribution;
参考文献
Adcock, James L.; Evans, William D.
Journal of Organic Chemistry, 1984 , vol. 49, # 15 p. 2719 - 2723
