2,3-二甲基-2,3-环氧丁烷合成路线 (共 115 条)
反应条件
hydrogenchloride
bei Abschluss von Luftfeuchtigkeit, anschl. Behandeln mit Natrium und n-Kalilauge;
参考文献
Delacre
Bulletin de la Societe Chimique de France, 1908 , vol. <4> 3, p. 209
参考文献
O'Brien, Brian A.; Lam, William Y.; DesMarteau, Darryl D.
Journal of Organic Chemistry, 1986 , vol. 51, # 23 p. 4466 - 4470
反应条件
(TPPC2cap)FeIIISbF6 in dichloromethane
12 h; Ambient temperature; Mechanism;
参考文献
Dicken, C. Michael; Lu, Fu-Lung; Bruice, Thomas C.
Tetrahedron Letters, 1986 , vol. 27, # 49 p. 5967 - 5970
反应条件
oxygen
T=500°C; Further byproducts given;
参考文献
Baldwin, Robert R.; Drewery, George R.; Walker, Raymond W.
Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, 1984 , vol. 80, p. 3195 - 3207
反应条件
tetrachloromethane; potassium carbonate; triphenylphosphine
24 h; Heating; Title compound not separated from byproducts;
参考文献
Barry, Carey N.; Evans, Slayton A.
Tetrahedron Letters, 1983 , vol. 24, # 7 p. 661 - 664
反应条件
phenyl(phenylazo)methyl hydroperoxide in benzene-d6
T=34°C; further hydroperoxides;
参考文献
Baumstark, A. L.; Vasquez, P. C.
Tetrahedron Letters, 1983 , vol. 24, # 2 p. 123 - 126
反应条件
hydrogenchloride; 1,1,2,2-tetramethylethylene; 3-chloro-benzenecarboperoxoic acid
1.) dichloromethane, 25 deg C, 30 min; Multistep reaction. Further byproducts given. Title compound not separated from byproducts;
参考文献
Schmid, George H.; Strukelj, Mark; Dalipi, Snezana; Ryan, M.Dominic
Journal of Organic Chemistry, 1987 , vol. 52, # 12 p. 2403 - 2407
反应条件
in hexane
0.0522222 h;
参考文献
Murray, Robert W.; Kong, Wei; Rajadhyaksha, Shirish N.
Journal of Organic Chemistry, 1993 , vol. 58, # 2 p. 315 - 321
反应条件
oxygen in gas
T=69.9°C; P=200 Torr; 1.33333 h; Irradiationdifferent time, temperature and oxygen pressure; Product distribution;
参考文献
Morgan, Morag E.; Osborne, David A.; Waddington, David J.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1984 , p. 1869 - 1873
反应条件
ozone in hexane
T=0°C; variation of concentration and temperature, other solvents or without solvent, addition of CH3CHO and phenanthrene; Product distributionMechanism;
参考文献
Murray, Robert W.; Kong, Wei; Rajadhyaksha, Shirish N.
Journal of Organic Chemistry, 1993 , vol. 58, # 2 p. 315 - 321