1: S2Cl2, POCl3 2: 68 percent / tetrahydrofuran / 11 h / Ambient temperature; Irradiation 3: 76 percent / H2O / dimethylsulfoxide View Scheme

1: 76 percent / LDA / tetrahydrofuran / 1.) -78 deg C, 10 min, 2.) room temperature, 4 h 2: 98 percent / 4-(dimethylamino)pyridine, Et3N / CH2Cl2 / 72 h / Ambient temperature 3: 63 percent / LDA / tetrahydrofuran / 0.5 h / -78 °C 4: 68 percent / phenylmercuric perchlorate / tetrahydrofuran / 0.33 h / Ambient temperature View Scheme

diphosphorus pentasulfide; xylene

Multistep reaction; reaction with OHC(.), radiolysis; with K3FeCN6(oxidat.); G-values (rad.-chem. yields); various pH; Quantum yieldRate constant;

water; oxygen; Nitrous oxide Irradiationradiolysis; Product distribution;

暂无反应条件数据

barium dihydroxide; water

sulfur T=180 - 190°C;

water; oxygen; Nitrous oxide Irradiationradiolysis; Product distribution;

1.1: bromine / 1,2-dichloro-benzene / 150 °C 2.1: triethylamine / chloroform; acetone / 4 h / 4 °C 3.1: hydrogenchloride / diethyl ether; methanol / 2 h / |Reflux 4.1: boron trifluoride diethyl etherate / dichloromethane / 16 h / 20 °C 5.1: n-butyllithium / tetrahydrofuran; hexane / 0.03 h / -78 °C 5.2: -78 - 20 °C 6.1: n-butyllithium / tetrahydrofuran; hexane / -78 - 20 °C 7.1: boron trichloride / dichloromethane / 0.17 h / 0 °C 8.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 0.17 h / 0 °C 8.2: 9 h / 0 - 20 °C View Scheme