2-溴-2-环己烯-1-酮合成路线 （共 24 条）
反应条件
bromine in chloroform
30 h;
参考文献
Engman, Lars; Toernroos, Karl Wilhelm
Journal of Organometallic Chemistry, 1990 , vol. 391, # 2 p. 165 - 178
反应条件
acetic acid; lithium bromide in acetonitrile
T=80°C;
参考文献
Ponaras, Anthony A.; Zaim, Oemer
Journal of Organic Chemistry, 1986 , vol. 51, # 24 p. 4741 - 4743
反应条件
oxygen; caesium carbonate; (-)-sparteine in chloroform
T=23°C; P=760.051 Torr; 33 h; Molecular sieve; optical yield given as percent ee;
参考文献
Ebner, David C.; Bagdanoff, Jeffrey T.; Ferreira, Eric M.; McFadden, Ryan M.; Caspi, Daniel D.; Trend, Raissa M.; Stoltz, Brian M.
Chemistry - A European Journal, 2009 , vol. 15, # 47 p. 12978 - 12992
反应条件
bromine; triethylamine in dichloromethane
T=0 - 20°C;
参考文献
Sadak, Ali Enis; Arslan, Tayfun; Celebioglu, Neslihan; Saracoglu, Nurullah
Tetrahedron, 2010 , vol. 66, # 17 p. 3214 - 3221
反应条件
sodium hydrogencarbonate
Ambient temperature;
参考文献
Chow, Yuan L.; Bakker, Bert H.
Canadian Journal of Chemistry, 1982 , vol. 60, p. 2268 - 2273
反应条件
1: 1 M aq. LiOH / CHCl3 / Ambient temperature
2: 91 percent Chromat. / LiBr, acetic acid / acetonitrile / 80 °C
View Scheme
参考文献
Ponaras, Anthony A.; Zaim, Oemer
Journal of Organic Chemistry, 1986 , vol. 51, # 24 p. 4741 - 4743
反应条件
1: Et3N / diethyl ether / 3 h / Ambient temperature
2: 67 percent / Br2 / CHCl3 / 30 h
View Scheme
参考文献
Engman, Lars; Toernroos, Karl Wilhelm
Journal of Organometallic Chemistry, 1990 , vol. 391, # 2 p. 165 - 178
反应条件
1: CH2Cl2 / Ambient temperature
2: 83 percent / 30percent H2O2, pyridine / CH2Cl2 / 30 °C
View Scheme
参考文献
Buckley, Daniel J.; McKervey, M. Anthony
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1985 , p. 2193 - 2200
反应条件
toluene-4-sulfonic acid in benzene
24 h; Heating;
参考文献
Shih, Chuan; Fritzen, Edward L.; Swenton, John S.
Journal of Organic Chemistry, 1980 , vol. 45, # 22 p. 4462 - 4471
反应条件
1.1: triphenylphosphine; copper(I) bromide / toluene / 0.08 h / Inert atmosphere; Cooling with acetone-dry ice
1.2: -60 - 20 °C / Inert atmosphere
2.1: sodium hydroxide / ethanol; water / 4.5 h / 20 °C / Inert atmosphere; Reflux
View Scheme
参考文献
Xu, Xiaoying; Li, Xiang; Wang, Anjie; Sun, Yinyong; Schweizer, W. Bernd; Prins, Roel
Helvetica Chimica Acta, 2011 , vol. 94, # 10 p. 1754 - 1763
