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63148-62-9
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471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
50910-08-2
合成路线
（共 12 条）
109-04-6
邻溴吡啶
+
122-39-4
二苯胺
→
反应条件
50910-08-2
反应条件
sodium t-butanolate; palladium diacetate in toluene T=80°C; Buchwald-Hartwig amination; 24 h;
参考文献
Topchiy, Maxim A.; Asachenko, Andrey F.; Nechaev, Mikhail S.
European Journal of Organic Chemistry, 2014 , vol. 2014, # 16 p. 3319 - 3322
109-09-1
2-氯吡啶
+
122-39-4
二苯胺
→
反应条件
50910-08-2
反应条件
sodium t-butanolate; tris(dibenzylideneacetone)dipalladium (0); P(i-BuNCH2CH2)3N in toluene T=100°C; Buchwald-Hartwig amination; 20 h;
参考文献
Urgaonkar, Sameer; Verkade, John G.
Journal of Organic Chemistry, 2004 , vol. 69, # 26 p. 9135 - 9142
504-29-0
2-氨基吡啶
+
591-50-4
碘苯
→
反应条件
50910-08-2
+
6631-37-4
2-苯胺基吡啶
反应条件
potassium phosphate; copper(l) iodide in dimethyl sulfoxide T=110°C; Ullmann Condensation; 24 h; Inert atmosphereGlovebox;
参考文献
Gueell, Imma; Ribas, Xavi
European Journal of Organic Chemistry, 2014 , vol. 2014, # 15 p. 3188 - 3195
504-29-0
2-氨基吡啶
+
108-86-1
溴代苯
→
反应条件
50910-08-2
+
6631-37-4
2-苯胺基吡啶
反应条件
C46H58Br2N4O10Pd; potassium tert-butylate in ethylene glycol dimethyl ether T=80°C; 15 h; Inert atmosphereBuchwald-Hartwig amination;
参考文献
Dogan, Oeznur; Demir, Serpil; Oezdemir, Ismail; Cetinkaya, Bekir
Applied Organometallic Chemistry, 2011 , vol. 25, # 3 p. 163 - 167
591-50-4
碘苯
+
6631-37-4
2-苯胺基吡啶
→
反应条件
50910-08-2
反应条件
potassium phosphate; copper(l) iodide in dimethyl sulfoxide T=110°C; Ullmann Condensation; 8 h; Inert atmosphereGlovebox;
参考文献
Gueell, Imma; Ribas, Xavi
European Journal of Organic Chemistry, 2014 , vol. 2014, # 15 p. 3188 - 3195
6631-37-4
2-苯胺基吡啶
→
反应条件
50910-08-2
+
1256380-82-1
反应条件
palladium diacetate; p-benozquinone; silver(l) oxide in tert-butyl alcohol T=80 - 90°C; 4 h; Overall yield = 13 percent;
参考文献
Chu, Jean-Ho; Huang, Hao-Ping; Hsu, Wen-Ting; Chen, Shih-Tien; Wu, Ming-Jung
Organometallics, 2014 , vol. 33, # 5 p. 1190 - 1204
6631-37-4
2-苯胺基吡啶
→
反应条件
50910-08-2
+
23866-67-3
+
1256380-82-1
反应条件
copper diacetate; palladium diacetate; p-benozquinone in N,N-dimethyl-formamide T=80 - 90°C; 4 h; Overall yield = 56 percent;
参考文献
Chu, Jean-Ho; Huang, Hao-Ping; Hsu, Wen-Ting; Chen, Shih-Tien; Wu, Ming-Jung
Organometallics, 2014 , vol. 33, # 5 p. 1190 - 1204
504-29-0
2-氨基吡啶
+
591-50-4
碘苯
→
反应条件
50910-08-2
反应条件
1: potassium phosphate; copper(l) iodide / dimethyl sulfoxide / 24 h / 110 °C / |Inert atmosphere; |Glovebox 2: potassium phosphate; copper(l) iodide / dimethyl sulfoxide / 8 h / 110 °C / |Inert atmosphere; |Glovebox View Scheme
参考文献
Gueell, Imma; Ribas, Xavi
European Journal of Organic Chemistry, 2014 , vol. 2014, # 15 p. 3188 - 3195
109-04-6
邻溴吡啶
→
反应条件
50910-08-2
反应条件
1: potassium tert-butylate; tris-(dibenzylideneacetone)dipalladium(0); bis[2-(diphenylphosphino)phenyl] ether / toluene / 100 °C / |Inert atmosphere 2: palladium diacetate; p-benozquinone; silver(l) oxide / tert-butyl alcohol / 4 h / 80 - 90 °C View Scheme
参考文献
Chu, Jean-Ho; Huang, Hao-Ping; Hsu, Wen-Ting; Chen, Shih-Tien; Wu, Ming-Jung
Organometallics, 2014 , vol. 33, # 5 p. 1190 - 1204
74497-02-2
→
反应条件
50910-08-2
反应条件
1: potassium tert-butylate; tris-(dibenzylideneacetone)dipalladium(0); bis[2-(diphenylphosphino)phenyl] ether / toluene / 100 °C / |Inert atmosphere 2: palladium diacetate; p-benozquinone; silver(l) oxide / tert-butyl alcohol / 4 h / 80 - 90 °C View Scheme
参考文献
Chu, Jean-Ho; Huang, Hao-Ping; Hsu, Wen-Ting; Chen, Shih-Tien; Wu, Ming-Jung
Organometallics, 2014 , vol. 33, # 5 p. 1190 - 1204
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