对氨基苯基-BETA-D-半乳糖苷合成路线 (共 9 条)
反应条件
hydrogen; palladium on activated charcoal in methanol T=20°C; 3 h;
参考文献
Amaike; Kobayashi; Shinkai
Bulletin of the Chemical Society of Japan, 2000 , vol. 73, # 11 p. 2553 - 2558
参考文献
Bayer Aktiengesellschaft
Patent: US6271342 B1, 2001 ;
反应条件
1: barium hydroxide; water 2: platinum; ethanol / Hydrogenation View Scheme
参考文献
Goebel; Avery
Journal of Experimental Medicine, 1929 , vol. 50, p. 521,528
反应条件
1: palladium on activated charcoal; sodium tetrahydroborate / dichloromethane; methanol / 0.25 h / 0 °C 2: sodium methylate; methanol / 16 h / 20 °C View Scheme
参考文献
Jayasundara, Dilushan R.; Duff, Thomas; Angione, M. Daniela; Bourke, Jean; Murphy, Deirdre M.; Scanlan, Eoin M.; Colavita, Paula E.
Chemistry of Materials, 2013 , vol. 25, # 20 p. 4122 - 4128
反应条件
1: boron trifluoride diethyl etherate / dichloromethane / 2 h / -20 °C 2: palladium on activated charcoal; sodium tetrahydroborate / dichloromethane; methanol / 0.25 h / 0 °C 3: sodium methylate; methanol / 16 h / 20 °C View Scheme
参考文献
Jayasundara, Dilushan R.; Duff, Thomas; Angione, M. Daniela; Bourke, Jean; Murphy, Deirdre M.; Scanlan, Eoin M.; Colavita, Paula E.
Chemistry of Materials, 2013 , vol. 25, # 20 p. 4122 - 4128
反应条件
1: 1,8-diazabicyclo[5.4.0]undec-7-ene / dichloromethane / 3 h / 20 °C 2: boron trifluoride diethyl etherate / dichloromethane / 2 h / -20 °C 3: palladium on activated charcoal; sodium tetrahydroborate / dichloromethane; methanol / 0.25 h / 0 °C 4: sodium methylate; methanol / 16 h / 20 °C View Scheme
参考文献
Jayasundara, Dilushan R.; Duff, Thomas; Angione, M. Daniela; Bourke, Jean; Murphy, Deirdre M.; Scanlan, Eoin M.; Colavita, Paula E.
Chemistry of Materials, 2013 , vol. 25, # 20 p. 4122 - 4128
反应条件
1: benzylamine / tetrahydrofuran / 16 h / 20 °C 2: 1,8-diazabicyclo[5.4.0]undec-7-ene / dichloromethane / 3 h / 20 °C 3: boron trifluoride diethyl etherate / dichloromethane / 2 h / -20 °C 4: palladium on activated charcoal; sodium tetrahydroborate / dichloromethane; methanol / 0.25 h / 0 °C 5: sodium methylate; methanol / 16 h / 20 °C View Scheme
参考文献
Jayasundara, Dilushan R.; Duff, Thomas; Angione, M. Daniela; Bourke, Jean; Murphy, Deirdre M.; Scanlan, Eoin M.; Colavita, Paula E.
Chemistry of Materials, 2013 , vol. 25, # 20 p. 4122 - 4128
反应条件
methanol; sodium methylate T=20°C; 16 h;
参考文献
Jayasundara, Dilushan R.; Duff, Thomas; Angione, M. Daniela; Bourke, Jean; Murphy, Deirdre M.; Scanlan, Eoin M.; Colavita, Paula E.
Chemistry of Materials, 2013 , vol. 25, # 20 p. 4122 - 4128
反应条件
biotinylated Escherichia coli β-galactosidase in various solvent(s) Enzymatic reaction; Enzyme kinetics; Further Variations:reactant concentrations;
参考文献
Limoges, Benoit; Marchal, Damien; Mavre, Francois; Saveant, Jean-Michel
Journal of the American Chemical Society, 2006 , vol. 128, # 18 p. 6014 - 6015