2-苯基-2H- 1,2,3-三氮唑合成路线 （共 19 条）
反应条件
sulfuric acid; nitric acid
参考文献
Riebsomer
Journal of Organic Chemistry, 1948 , vol. 13, p. 815,817
参考文献
Smiglak, Marcin; Corey Hines; Singh, Shailendra; Wilsion, Timothy B.; Vincek, Adam S.; Kirichenko, Kostyantyn; Katritzky, Alan R.; Rogers, Robin D.
Chemistry - A European Journal, 2010 , vol. 16, # 5 p. 1572 - 1584
反应条件
caesium carbonate; copper(II) oxide; iron (III) acetylacetonate in N,N-dimethyl-formamide
T=90°C; 30 h;
参考文献
Taillefer, Marc; Xia, Ning; Ouali, Armelle
Angewandte Chemie - International Edition, 2007 , vol. 46, # 6 p. 934 - 936
反应条件
copper(II) sulfate in water
T=75 - 80°C; 6.5 h;
参考文献
Matter, Hans; Schudok, Manfred; Schwab, Wilfried; Thorwart, Werner; Barbier, Denis; Billen, Guenter; Haase, Burkhard; Neises, Bernhard; Weithmann, Klaus-Ulrich; Wollmann, Theo
Bioorganic and Medicinal Chemistry, 2002 , vol. 10, # 11 p. 3529 - 3544
反应条件
3,4,5,6-tetramethyl-t-Bu-X-Phos; potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0) in toluene
T=120°C; 5 h; Inert atmosphere; regioselective reaction;
参考文献
Ueda, Satoshi; Ali, Siraj; Fors, Brett P.; Buchwald, Stephen L.
Journal of Organic Chemistry, 2012 , vol. 77, # 5 p. 2543 - 2547
反应条件
caesium carbonate; Fe(acac)3; copper(II) oxide in N,N-dimethyl-formamide
T=90°C; 30 h; sealed tube; Conversion of starting material;
参考文献
CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (C.N.R.S.); Ecole Nationale Superieure de Chimie de Montpellier
Patent: WO2008/4088 A2, 2008 ;
Location in patent: Page/Page column 49-50 ;
反应条件
copper(II) bis(trifluoromethanesulfonate) in toluene
T=110°C; 5 h; Inert atmosphere;
参考文献
Myachina; Ermakova; Kuznetsova; Sultangareev; Larina; Klyba; Suchanov; Trofimov
Chemistry of Heterocyclic Compounds, 2010 , vol. 46, # 1 p. 79 - 81
反应条件
1: 81 percent / lead tetraacetate / CH2Cl2 / 0 °C
2: CH2Cl2 / Ambient temperature
View Scheme
参考文献
Kaihoh, Terumitsu; Itoh, Takashi; Yamaguchi, Kentaro; Ohsawa, Akio
Journal of the Chemical Society, Chemical Communications, 1988 , # 24 p. 1608 - 1609
反应条件
1: 94 percent / CH2Cl2 / 72 h
2: 5 percent / sodium hydride / 2 h / Heating
View Scheme
参考文献
Begtrup, Mikael; Holm, John
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1981 , p. 503 - 513
反应条件
1: 80 percent / copper(II) sulphate / pyridine; H2O / 4 h / Heating
2: 94 percent / CH2Cl2 / 72 h
3: 5 percent / sodium hydride / 2 h / Heating
View Scheme
参考文献
Begtrup, Mikael; Holm, John
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1981 , p. 503 - 513
