1: trans-1,2-dichloroethylene With n-butyllithium in tetrahydrofuran; hexane T=0°C; 2: chloro-diphenylphosphine in tetrahydrofuran; hexane T=0°C; 3: chloro-diphenylphosphine Further stages;
参考文献
Nagaki, Aiichiro; Matsuo, Chika; Kim, Songhee; Saito, Kodai; Miyazaki, Atsuo; Yoshida, Jun-Ichi
Angewandte Chemie - International Edition, 2012 , vol. 51, # 13 p. 3245 - 3248
Hartmann et al.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1956 , vol. 287, p. 261,264
→
反应条件
in hexane The complex and a slight excess of C2(PPh2)2 are refluxed in hexane for 5 min (N2). 30percent decompn.; The reaction soln. was filtered and concd. to small vol. under reduced pressure then subjected to preparative thin layer chromy. (silica gel; light petroleum/diethyl ether).;
参考文献
Journal of Organometallic Chemistry, , vol. 342, p. 97 - 110
