(+)-对薄荷-2,8-二烯 (3R,6R)-3-异丙烯基-6-甲基环己烯合成路线 （共 12 条）
反应条件
sulfuric acid; sodium nitrite
参考文献
Cocker,W. et al.
Journal of the Chemical Society [Section] C: Organic, 1969 , p. 1302 - 1308
参考文献
Romanenko; Starokon'; Panov; Tkacheva
Russian Chemical Bulletin, 2007 , vol. 56, # 6 p. 1239 - 1243
反应条件
1.1: dicyclohexylborane / tetrahydrofuran / 168 h / 0 °C 1.2: 82 percent / H2O2; OH(1-) 2.1: 80 percent / CrO3; H2SO4 / acetone / 0 °C 3.1: KI; NaHCO3 (aq.) / 48 h 4.1: 72 percent / (Me3Si)3SiH; AIBN / toluene 5.1: BF3*Et2O / CH2Cl2 / 0 °C 6.1: NaOH (10 percent in MeOH) / Heating 7.1: diethyl ether 8.1: 89 percent / PCC / CH2Cl2 / 0 °C 9.1: 45 percent / KHMDS / tetrahydrofuran; hexamethylphosphoric acid triamide / 24 h / 50 °C 10.1: 80 percent / HgCl2; CaCO3 / acetonitrile; H2O 11.1: O2; Rose Bengal; HCl (dry) / methanol / 4 h / -78 °C / UV-irradiation 11.2: 10 percent / HClO4 (70 percent in ether) / 28 h View Scheme
参考文献
Yadav; Satheesh Babu; Sabitha
Tetrahedron Letters, 2003 , vol. 44, # 2 p. 387 - 389
反应条件
bis-triphenylphosphine-palladium(II) chloride; triphenylphosphine; tin(ll) chloride in toluene T=97°C; P=30002.4 Torr; 16 h;
参考文献
Journal of Organometallic Chemistry, , vol. 480, # 1-2 p. 91 - 102
反应条件
potassium tert-butylate in dimethyl sulfoxide T=50°C; 30 h; other reaction times; MechanismProduct distribution;
参考文献
Buinova, E. F.; Urbanovich, T. R.; Udarov, B. G.; Izotova, L. V.
Chemistry of Natural Compounds, 1982 , vol. 18, p. 555 - 559
Khimiya Prirodnykh Soedinenii, 1982 , vol. 18, # 5 p. 587 - 591
反应条件
bis-triphenylphosphine-palladium(II) chloride; triphenylphosphine; tin(ll) chloride in toluene T=97°C; P=30002.4 Torr; 16 h;
参考文献
Journal of Organometallic Chemistry, , vol. 480, # 1-2 p. 91 - 102
反应条件
potassium tert-butylate in dimethyl sulfoxide T=50°C; 30 h; other reaction times; MechanismProduct distribution;
参考文献
Buinova, E. F.; Urbanovich, T. R.; Udarov, B. G.; Izotova, L. V.
Chemistry of Natural Compounds, 1982 , vol. 18, p. 555 - 559
Khimiya Prirodnykh Soedinenii, 1982 , vol. 18, # 5 p. 587 - 591
反应条件
potassium tert-butylate in dimethyl sulfoxide T=50°C; 30 h; other reaction times; MechanismProduct distribution;
参考文献
Buinova, E. F.; Urbanovich, T. R.; Udarov, B. G.; Izotova, L. V.
Chemistry of Natural Compounds, 1982 , vol. 18, p. 555 - 559
Khimiya Prirodnykh Soedinenii, 1982 , vol. 18, # 5 p. 587 - 591
反应条件
potassium tert-butylate in dimethyl sulfoxide
T=50°C; 30 h; other reaction times; MechanismProduct distribution;
参考文献
Buinova, E. F.; Urbanovich, T. R.; Udarov, B. G.; Izotova, L. V.
Chemistry of Natural Compounds, 1982 , vol. 18, p. 555 - 559
Khimiya Prirodnykh Soedinenii, 1982 , vol. 18, # 5 p. 587 - 591
反应条件
potassium tert-butylate in dimethyl sulfoxide
T=50°C; 30 h; other reaction times; MechanismProduct distribution;
参考文献
Buinova, E. F.; Urbanovich, T. R.; Udarov, B. G.; Izotova, L. V.
Chemistry of Natural Compounds, 1982 , vol. 18, p. 555 - 559
Khimiya Prirodnykh Soedinenii, 1982 , vol. 18, # 5 p. 587 - 591
