1: K3Fe(CN)6, K2CO3, OsO4, (DHQD)2-PHAL, MeSO2NH2 / H2O; 2-methyl-propan-2-ol; toluene / 28 h / 0 °C 2: HCOONH4 / Pd-C / ethanol / 6 h / Heating 3: Jone's reagent / acetone / 8 h / 0 °C View Scheme
参考文献
Nandanan; Jayachandran; Phukan, Prodeep; Pais, Godwin C. G.; Sudalai
Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 1998 , vol. 37, # 12 p. 1221 - 1227
1: 90 percent / POCl3, Py / CH2Cl2 / 0 - 25 °C 2: K3Fe(CN)6, K2CO3, OsO4, (DHQD)2-PHAL, MeSO2NH2 / H2O; 2-methyl-propan-2-ol; toluene / 28 h / 0 °C 3: HCOONH4 / Pd-C / ethanol / 6 h / Heating 4: Jone's reagent / acetone / 8 h / 0 °C View Scheme
参考文献
Nandanan; Jayachandran; Phukan, Prodeep; Pais, Godwin C. G.; Sudalai
Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 1998 , vol. 37, # 12 p. 1221 - 1227
1: HCOONH4 / Pd-C / ethanol / 6 h / Heating 2: Jone's reagent / acetone / 8 h / 0 °C View Scheme
参考文献
Nandanan; Jayachandran; Phukan, Prodeep; Pais, Godwin C. G.; Sudalai
Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 1998 , vol. 37, # 12 p. 1221 - 1227
Jone's reagent in acetone T=0°C; 8 h; Yield givenYields of byproduct given. Title compound not separated from byproducts;
参考文献
Nandanan; Jayachandran; Phukan, Prodeep; Pais, Godwin C. G.; Sudalai
Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 1998 , vol. 37, # 12 p. 1221 - 1227
sodium hydroxide; potassium permanganate; sodium periodate; potassium carbonate in water; Petroleum ether Yield given. Yields of byproduct given. Title compound not separated from byproducts;
sodium hydroxide; potassium permanganate; sodium periodate; potassium carbonate in water; tert-butyl alcohol Yield given. Yields of byproduct given. Title compound not separated from byproducts;
