hydrogen fluoride in water

1: With water; oxygen; lipoxygenase from rice T=25°C; 1 h; Aqueous phosphate buffer; 2: With water; areneoxide synthase from linseed 0.5 h; 3: With hydrogenchloride in water pH=3.0;

Lipase PS in phosphate buffer; acetone pH=7.0;

1.1: O3 / methanol; CH2Cl2 / -17 °C 1.2: Me2S / methanol; CH2Cl2 / -17 °C 2.1: tetrahydrofuran / -25 °C 3.1: MCPBA; aq. NaHCO3 / CH2Cl2 4.1: 45.6 percent / imidazole / dimethylformamide 5.1: 87.6 percent / n-BuLi; BF3.Et2O / tetrahydrofuran / -50 °C 6.1: 49.4 percent / H2 / Lindlar's catalyst / toluene 7.1: 82.1 percent / aq. HF / acetonitrile 8.1: 68.8 percent / lipase PS / aq. phosphate buffer; acetone / pH 7.0 View Scheme

1: tetrahydrofuran / -25 °C 2: MCPBA; aq. NaHCO3 / CH2Cl2 3: 45.6 percent / imidazole / dimethylformamide 4: 87.6 percent / n-BuLi; BF3.Et2O / tetrahydrofuran / -50 °C 5: 49.4 percent / H2 / Lindlar's catalyst / toluene 6: 82.1 percent / aq. HF / acetonitrile 7: 68.8 percent / lipase PS / aq. phosphate buffer; acetone / pH 7.0 View Scheme

1: MCPBA; aq. NaHCO3 / CH2Cl2 2: 45.6 percent / imidazole / dimethylformamide 3: 87.6 percent / n-BuLi; BF3.Et2O / tetrahydrofuran / -50 °C 4: 49.4 percent / H2 / Lindlar's catalyst / toluene 5: 82.1 percent / aq. HF / acetonitrile 6: 68.8 percent / lipase PS / aq. phosphate buffer; acetone / pH 7.0 View Scheme

1: 45.6 percent / imidazole / dimethylformamide 2: 87.6 percent / n-BuLi; BF3.Et2O / tetrahydrofuran / -50 °C 3: 49.4 percent / H2 / Lindlar's catalyst / toluene 4: 82.1 percent / aq. HF / acetonitrile 5: 68.8 percent / lipase PS / aq. phosphate buffer; acetone / pH 7.0 View Scheme

1: 87.6 percent / n-BuLi; BF3.Et2O / tetrahydrofuran / -50 °C 2: 49.4 percent / H2 / Lindlar's catalyst / toluene 3: 82.1 percent / aq. HF / acetonitrile 4: 68.8 percent / lipase PS / aq. phosphate buffer; acetone / pH 7.0 View Scheme

1: 49.4 percent / H2 / Lindlar's catalyst / toluene 2: 82.1 percent / aq. HF / acetonitrile 3: 68.8 percent / lipase PS / aq. phosphate buffer; acetone / pH 7.0 View Scheme

1: 82.1 percent / aq. HF / acetonitrile 2: 68.8 percent / lipase PS / aq. phosphate buffer; acetone / pH 7.0 View Scheme