十二碳-11-烯-1-醛合成路线 （共 14 条）
反应条件
aluminum oxide
Heating;
参考文献
Cottier,L.; Descotes,G.
Bulletin de la Societe Chimique de France, 1972 , p. 1072 - 1076
反应条件
1: piperidine acetate / xylene / 4 h / Heating
2: TsOH / 24 h / Ambient temperature
3: 93 percent / DIBAH / diethyl ether; toluene / 1.5 h / -20 °C
4: 97 percent / pyridine / 18 h / -5 - 0 °C
5: 82 percent / LiAlH4 / diethyl ether / 1.5 h
View Scheme
参考文献
Odinokov, V. N.; Ishmuratov, G. Yu.; Vakhidov, R. R.; Berg, A. A.; Muslukhov, R. R.; Tolstikov, G. A.
Chemistry of Natural Compounds, 1992 , vol. 28, # 2 p. 237 - 240
Khimiya Prirodnykh Soedinenii, 1992 , # 2 p. 272 - 276
反应条件
1: 1.) Mg, I2, 1,2-dibromo-ethane / 1.) THF, reflux; 2.) THF, 0 deg C, 1 h
2: 76 percent / MnO2 / hexane / 24 h
View Scheme
参考文献
Spanton,S.G.; Prestwich,G.D.
Tetrahedron, 1982 , vol. 38, p. 1921
反应条件
piperidinium acetate in xylene
4 h; Heating;
参考文献
Odinokov, V. N.; Ishmuratov, G. Yu.; Vakhidov, R. R.; Berg, A. A.; Muslukhov, R. R.; Tolstikov, G. A.
Chemistry of Natural Compounds, 1992 , vol. 28, # 2 p. 237 - 240
Khimiya Prirodnykh Soedinenii, 1992 , # 2 p. 272 - 276
