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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
4-联苯硼酸
合成路线
(共 120 条)
474688-73-8
9-溴-10-(2-萘基)蒽
+
5122-94-1
4-联苯硼酸
→
反应条件
862501-00-6
反应条件
bis-triphenylphosphine-palladium(II) chloride in toluene 0.25 h; Heating / refluxSonication;
参考文献
Eastman Kodak Company
Patent: US2005/245752 A1, 2005 ;
Location in patent: Page/Page column 8 ;
5122-94-1
4-联苯硼酸
+
29913-00-6
→
反应条件
79447-11-3
反应条件
sodium carbonate; triphenylphosphine; palladium diacetate in toluene T=100°C; Suzuki cross-coupling; 12 h;
参考文献
Lim, Kyoung-Chan; Hong, Young-Taek; Kim, Sunggak
Synlett, 2006 , # 12 p. 1851 - 1854
5122-94-1
4-联苯硼酸
→
反应条件
922525-75-5
反应条件
potassium carbonate; tetrakis(triphenylphosphine) palladium(0) in ethanol; toluene T=90°C; Suzuki-Miyaura coupling; 24 h;
参考文献
Garcia, Marcos D.; Wilson, A. James; Emmerson, Daniel P.G.; Jenkins, Paul R.; Mahale, Sachin; Chaudhuri, Bhabatosh
Organic and Biomolecular Chemistry, 2006 , vol. 4, # 24 p. 4478 - 4484
906067-46-7
+
5122-94-1
4-联苯硼酸
→
反应条件
922525-76-6
反应条件
potassium carbonate; tetrakis(triphenylphosphine) palladium(0) in ethanol; toluene T=90°C; Suzuki-Miyaura coupling; 24 h;
参考文献
Garcia, Marcos D.; Wilson, A. James; Emmerson, Daniel P.G.; Jenkins, Paul R.; Mahale, Sachin; Chaudhuri, Bhabatosh
Organic and Biomolecular Chemistry, 2006 , vol. 4, # 24 p. 4478 - 4484
906067-45-6
+
5122-94-1
4-联苯硼酸
→
反应条件
922525-77-7
反应条件
potassium carbonate; tetrakis(triphenylphosphine) palladium(0) in ethanol; toluene T=90°C; Suzuki-Miyaura coupling; 24 h;
参考文献
Garcia, Marcos D.; Wilson, A. James; Emmerson, Daniel P.G.; Jenkins, Paul R.; Mahale, Sachin; Chaudhuri, Bhabatosh
Organic and Biomolecular Chemistry, 2006 , vol. 4, # 24 p. 4478 - 4484
523-27-3
9,10-二溴蒽
+
5122-94-1
4-联苯硼酸
→
反应条件
43069-36-9
9,10-双[(1,1-联苯)-4-基]蒽
反应条件
tetrakis(triphenylphosphine) palladium(0); potassium carbonate in tetrahydrofuran; toluene T=60 - 98°C; 48 h;
参考文献
Park, Hyuntae; Lee, Jonghee; Kang, Il; Chu, Hye Yong; Lee, Jeong-Ik; Kwon, Soon-Ki; Kim, Yun-Hi
Journal of Materials Chemistry, 2012 , vol. 22, # 6 p. 2695 - 2700
95-56-7
邻溴苯酚
+
5122-94-1
4-联苯硼酸
→
反应条件
4731-97-9
反应条件
potassium phosphate; palladium diacetate; tris-(o-tolyl)phosphine in water; toluene T=100°C; 16 h; Inert atmosphere;
参考文献
Stemper, Jeremy; Isaac, Kevin; Pastor, Julien; Frison, Gilles; Retailleau, Pascal; Voituriez, Arnaud; Betzer, Jean-Francois; Marinetti, Angela
Advanced Synthesis and Catalysis, 2013 , vol. 355, # 18 p. 3613 - 3624
533-58-4
+
5122-94-1
4-联苯硼酸
→
反应条件
4731-97-9
反应条件
palladium diacetate; potassium carbonate in water; N,N-dimethyl-formamide T=20°C; Suzuki-Miyaura coupling; 5 h;
参考文献
Wei, Ye; Yoshikai, Naohiko
Organic Letters, 2011 , vol. 13, # 20 p. 5504 - 5507
38071-57-7
+
5122-94-1
4-联苯硼酸
→
反应条件
56316-86-0
反应条件
1: 4-bromo-2-(1-cyclohexenyl)thiophene With tetrakis(triphenylphosphine) palladium(0) in ethylene glycol dimethyl ether T=20°C; 0.166667 h; 2: 1,1'-Biphenyl-4-yl-boronic acid With sodium carbonate in ethylene glycol dimethyl ether 24 h; Heating; Further stages.;
参考文献
Dingemans, Theo J.; Murthy, N. Sanjeeva; Samulski, Edward T.
Journal of Physical Chemistry B, 2001 , vol. 105, # 37 p. 8845 - 8860
625-88-7
+
5122-94-1
4-联苯硼酸
→
反应条件
56316-86-0
反应条件
tetrakis(triphenylphosphine) palladium(0); sodium carbonate in benzene Arylation; 6 h; Heating;
参考文献
Hotta; Kimura; Lee; Tamaki
Journal of Heterocyclic Chemistry, 2000 , vol. 37, # 2 p. 281 - 286
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