Wighteone; 5,7,4'三羟基-6-异戊烯基异黄酮合成路线 （共 23 条）
反应条件
1: 91 percent / BCl3 / CH2Cl2 / 2.5 h / 20 - 25 °C
2: 72 percent / aq. sodium hydroxide / methanol; dioxane / 0.33 h / 25 °C
View Scheme
参考文献
Hossain, Mohammad M.; Tokuoka, Takanori; Yamashita, Kazuyo; Kawamura, Yasuhiko; Tsukayama, Masao
Synthetic Communications, 2006 , vol. 36, # 9 p. 1201 - 1211
反应条件
1: 57 percent / p-TsOH hydrate; acetic acid / toluene / 1.5 h / Heating
2: 91 percent / BCl3 / CH2Cl2 / 2.5 h / 20 - 25 °C
3: 72 percent / aq. sodium hydroxide / methanol; dioxane / 0.33 h / 25 °C
View Scheme
参考文献
Hossain, Mohammad M.; Tokuoka, Takanori; Yamashita, Kazuyo; Kawamura, Yasuhiko; Tsukayama, Masao
Synthetic Communications, 2006 , vol. 36, # 9 p. 1201 - 1211
反应条件
protein extract from Botrytis cinerea; NADPH in ethyl acetate
T=20°C; enzymatic reaction with Botrytis epoxidase; fungal metabolism of prenylated flavonoids; Product distribution;
参考文献
Tanaka, Mitsuharu; Tahara, Satoshi
Phytochemistry, 1997 , vol. 46, # 3 p. 433 - 439
