5,5-二甲基-2-苯基-1,3,2-二氧硼杂合成路线 （共 155 条）
反应条件
1: phenylboronic acid neopentylglycol ester With bis(1,5-cyclooctadiene)nickel (0); Ipr.HCl; cesium fluoride in 1,4-dioxane; toluene T=20°C; 0.5 h; Inert atmosphere; 2: 1-hydroxyindan With chlorobenzene in 1,4-dioxane; toluene T=60 - 80°C; Inert atmosphere;
参考文献
Maekawa, Takehisa; Sekizawa, Hiromi; Itami, Kenichiro
Angewandte Chemie - International Edition, 2011 , vol. 50, # 31 p. 7022 - 7026
反应条件
cesium fluoride; bis-triphenylphosphine-palladium(II) chloride in tetrahydrofuran T=80°C; 16 h;
参考文献
Lysen, Morten; Kelleher, Susan; Begtrup, Mikael; Kristensen, Jesper Langgaard
Journal of Organic Chemistry, 2005 , vol. 70, # 13 p. 5342 - 5343
反应条件
copper acetylacetonate; potassium tert-butylate; oxygen in toluene T=110°C; 2 h;
参考文献
Shen, Yan; Chen, Jiuxi; Liu, Miaochang; Ding, Jinchang; Gao, Wenxia; Huang, Xiaobo; Wu, Huayue
Chemical Communications, 2014 , vol. 50, # 33 p. 4292 - 4295
反应条件
bis(1,5-cyclooctadiene)nickel (0); potassium phosphate; tri-cyclo-hexyl-phosphine in tetrahydrofuran T=25°C; 12 h; Inert atmosphere;
参考文献
Journal of Organic Chemistry, , vol. 76, # 24 p. 9946 - 9955
反应条件
copper(l) iodide; lithium tert-butylate in N,N-dimethyl-formamide T=60°C; Suzuki-Miyauri coupling; 12 h; Inert atmosphere;
参考文献
Yang, Chu-Ting; Zhang, Zhen-Qi; Liu, Yu-Chen; Liu, Lei
Angewandte Chemie - International Edition, 2011 , vol. 50, # 17 p. 3904 - 3907
反应条件
copper(l) iodide; lithium tert-butylate in N,N-dimethyl-formamide T=110°C; Suzuki-Miyauri coupling; 24 h; Inert atmosphere;
参考文献
Yang, Chu-Ting; Zhang, Zhen-Qi; Liu, Yu-Chen; Liu, Lei
Angewandte Chemie - International Edition, 2011 , vol. 50, # 17 p. 3904 - 3907
反应条件
bis(1,5-cyclooctadiene)nickel (0); potassium tert-butylate; chlorobenzene; cesium fluoride; 1,3-bis(2,6-diisopropylphenyl)imidazolinium chloride in toluene T=80°C; 0.5 h; Inert atmosphere;
参考文献
Berini, Christophe; Navarro, Oscar
Chemical Communications, 2012 , vol. 48, # 10 p. 1538 - 1540
反应条件
1.1: bis(1,5-cyclooctadiene)nickel (0); Ipr.HCl; cesium fluoride / 1,4-dioxane; toluene / 0.5 h / 20 °C / Inert atmosphere 1.2: 10 h / 60 °C / Inert atmosphere 2.1: toluene / 14 h / 80 °C View Scheme
参考文献
Maekawa, Takehisa; Sekizawa, Hiromi; Itami, Kenichiro
Angewandte Chemie - International Edition, 2011 , vol. 50, # 31 p. 7022 - 7026
反应条件
in toluene T=80°C; 14 h;
参考文献
Maekawa, Takehisa; Sekizawa, Hiromi; Itami, Kenichiro
Angewandte Chemie - International Edition, 2011 , vol. 50, # 31 p. 7022 - 7026
反应条件
bis(1,5-cyclooctadiene)nickel (0); potassium tert-butylate; chlorobenzene; cesium fluoride; 1,3-bis(2,6-diisopropylphenyl)imidazolinium chloride in toluene T=80°C; 0.5 h; Inert atmosphere;
参考文献
Berini, Christophe; Navarro, Oscar
Chemical Communications, 2012 , vol. 48, # 10 p. 1538 - 1540
