5,5-二甲基-2-苯基-1,3,2-二氧硼杂合成路线 （共 155 条）
反应条件
copper(l) iodide; lithium tert-butylate in N,N-dimethyl-formamide T=20°C; Suzuki-Miyauri coupling; 24 h; Inert atmosphere;
参考文献
Angewandte Chemie - International Edition, , vol. 50, # 17 p. 3904 - 3907
反应条件
copper(l) iodide; lithium tert-butylate in N,N-dimethyl-formamide T=60°C; Suzuki-Miyauri coupling; 24 h; Inert atmosphere;
参考文献
Angewandte Chemie - International Edition, , vol. 50, # 17 p. 3904 - 3907
反应条件
copper(l) iodide; lithium tert-butylate in N,N-dimethyl-formamide T=60°C; Suzuki-Miyauri coupling; 24 h; Inert atmosphere;
参考文献
Angewandte Chemie - International Edition, , vol. 50, # 17 p. 3904 - 3907
反应条件
potassium tert-butylate; acetylacetone; copper(l) chloride in water; acetonitrile
T=80°C; 12 h; Inert atmosphere; regioselective reaction;
参考文献
Ohmiya, Hirohisa; Yokokawa, Natsumi; Sawamura, Masaya
Organic Letters, 2010 , vol. 12, # 10 p. 2438 - 2440
反应条件
oxygen; copper(l) chloride; lithium tert-butylate in N,N-dimethyl-formamide
T=100°C; P=760.051 Torr; 0.333333 h;
参考文献
Yang, Fanzhi; Xu, Zhaoqing; Wang, Zhe; Yu, Zhengkun; Wang, Rui
Chemistry - A European Journal, 2011 , vol. 17, # 23 p. 6321 - 6325
反应条件
[(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)Cu(OtBu)]; potassium tert-butylate in 1,4-dioxane
T=30°C; 20 h;
参考文献
Takatsu, Keishi; Shintani, Ryo; Hayashi, Tamio
Angewandte Chemie - International Edition, 2011 , vol. 50, # 24 p. 5548 - 5552
反应条件
copper(l) iodide; lithium tert-butylate in N,N-dimethyl-formamide
T=80°C; Suzuki-Miyauri coupling; 24 h; Inert atmosphere;
参考文献
Yang, Chu-Ting; Zhang, Zhen-Qi; Liu, Yu-Chen; Liu, Lei
Angewandte Chemie - International Edition, 2011 , vol. 50, # 17 p. 3904 - 3907
反应条件
copper(l) iodide; lithium tert-butylate in N,N-dimethyl-formamide
T=25°C; Suzuki-Miyauri coupling; 24 h; Inert atmosphere;
参考文献
Yang, Chu-Ting; Zhang, Zhen-Qi; Liu, Yu-Chen; Liu, Lei
Angewandte Chemie - International Edition, 2011 , vol. 50, # 17 p. 3904 - 3907
反应条件
copper(l) iodide; lithium tert-butylate in N,N-dimethyl-formamide
T=60°C; Suzuki-Miyauri coupling; 12 h; Inert atmosphere;
参考文献
Yang, Chu-Ting; Zhang, Zhen-Qi; Liu, Yu-Chen; Liu, Lei
Angewandte Chemie - International Edition, 2011 , vol. 50, # 17 p. 3904 - 3907
反应条件
1: phenylboronic acid neopentylglycol ester; pivalic acid sodium salt With silver carbonate; p-benozquinone; palladium diacetate in tert-butyl alcohol
T=120°C; 3 h;
2: With oxalyl dichloride in dichloromethane
T=0 - 20°C;
3: methanol With triethylamine in dichloromethane
T=0 - 20°C; 8 h; Further stages.;
参考文献
Giri, Ramesh; Maugel, Nathan; Li, Jiao-Jie; Wang, Dong-Hui; Breazzano, Steven P.; Saunders, Lindsey B.; Yu, Jin-Quan
Journal of the American Chemical Society, 2007 , vol. 129, # 12 p. 3510 - 3511
