5,5-二甲基-2-苯基-1,3,2-二氧硼杂合成路线 （共 155 条）
反应条件
1.1: Ag2CO3; K2HPO4; benzoquinone / Pd(OAc)2 / 2-methyl-propan-2-ol / 3 h / 120 °C
2.1: oxalyl chloride / CH2Cl2 / 0 - 20 °C
2.2: 38 percent / triethylamine / CH2Cl2 / 8 h / 0 - 20 °C
View Scheme
参考文献
Giri, Ramesh; Maugel, Nathan; Li, Jiao-Jie; Wang, Dong-Hui; Breazzano, Steven P.; Saunders, Lindsey B.; Yu, Jin-Quan
Journal of the American Chemical Society, 2007 , vol. 129, # 12 p. 3510 - 3511
反应条件
3,3-dimethyl-butan-2-one; ruthenium(II)-carbonyl-tris(triphenylphosphine) dihydride
Heating;
参考文献
Kakiuchi, Fumitoshi; Matsuura, Yusuke; Kan, Shintaro; Chatani, Naoto
Journal of the American Chemical Society, 2005 , vol. 127, # 16 p. 5936 - 5945
反应条件
dipotassium hydrogenphosphate; silver carbonate; p-benozquinone; palladium diacetate in tert-butyl alcohol
T=120°C; 3 h;
参考文献
Giri, Ramesh; Maugel, Nathan; Li, Jiao-Jie; Wang, Dong-Hui; Breazzano, Steven P.; Saunders, Lindsey B.; Yu, Jin-Quan
Journal of the American Chemical Society, 2007 , vol. 129, # 12 p. 3510 - 3511
反应条件
1: With bis(1,5-cyclooctadiene)nickel (0); Ipr.HCl; cesium fluoride in toluene
T=30 - 80°C; Inert atmosphere;
2: With water in diethyl ether; toluene
T=20°C; 1 h; Inert atmosphere;
参考文献
Bouffard, Jean; Itami, Kenichiro
Organic Letters, 2009 , vol. 11, # 19 p. 4410 - 4413
反应条件
bis(1,5-cyclooctadiene)nickel (0); potassium tert-butylate; chlorobenzene; cesium fluoride; 1,3-bis(2,6-diisopropylphenyl)imidazolinium chloride in toluene
T=80°C; 1.5 h; Inert atmosphere;
参考文献
Berini, Christophe; Navarro, Oscar
Chemical Communications, 2012 , vol. 48, # 10 p. 1538 - 1540
反应条件
3,3-dimethyl-butan-2-one; ruthenium(II)-carbonyl-tris(triphenylphosphine) dihydride
3 h; Inert atmosphereReflux;
参考文献
Kitazawa, Kentaroh; Kotani, Masashi; Kochi, Takuya; Langeloth, Michael; Kakiuchi, Fumitoshi
Journal of Organometallic Chemistry, 2010 , vol. 695, # 8 p. 1163 - 1167
反应条件
dipotassium hydrogenphosphate; silver carbonate; p-benozquinone; palladium diacetate in tert-butyl alcohol
T=120°C; 3 h;
参考文献
Giri, Ramesh; Maugel, Nathan; Li, Jiao-Jie; Wang, Dong-Hui; Breazzano, Steven P.; Saunders, Lindsey B.; Yu, Jin-Quan
Journal of the American Chemical Society, 2007 , vol. 129, # 12 p. 3510 - 3511
反应条件
silver carbonate; p-benozquinone; palladium diacetate in tert-butyl alcohol
T=120°C; 3 h;
参考文献
Giri, Ramesh; Maugel, Nathan; Li, Jiao-Jie; Wang, Dong-Hui; Breazzano, Steven P.; Saunders, Lindsey B.; Yu, Jin-Quan
Journal of the American Chemical Society, 2007 , vol. 129, # 12 p. 3510 - 3511
反应条件
dipotassium hydrogenphosphate; silver carbonate; p-benozquinone; palladium diacetate in tert-butyl alcohol
T=120°C; 3 h;
参考文献
Giri, Ramesh; Maugel, Nathan; Li, Jiao-Jie; Wang, Dong-Hui; Breazzano, Steven P.; Saunders, Lindsey B.; Yu, Jin-Quan
Journal of the American Chemical Society, 2007 , vol. 129, # 12 p. 3510 - 3511
反应条件
bis(1,5-cyclooctadiene)nickel (0); potassium tert-butylate; chlorobenzene; cesium fluoride; 1,3-bis(2,6-diisopropylphenyl)imidazolinium chloride in toluene
T=80°C; 5 h; Inert atmosphere;
参考文献
Berini, Christophe; Navarro, Oscar
Chemical Communications, 2012 , vol. 48, # 10 p. 1538 - 1540
