5,5-二甲基-2-苯基-1,3,2-二氧硼杂合成路线 （共 155 条）
反应条件
1.1: tri-ruthenium(0)dodecacarbonyl / 3,3-dimethyl-butan-2-one / 24 h / 140 °C / Inert atmosphere 2.1: tetrahydrofuran / 20 °C 2.2: 20 °C 3.1: methyl trifluoromethanesulfonate / dichloromethane / 0 °C 3.2: 6 h / 50 °C View Scheme
参考文献
Dastbaravardeh, Navid; Schnuerch, Michael; Mihovilovic, Marko D.
Organic Letters, 2012 , vol. 14, # 7 p. 1930 - 1933
反应条件
copper acetylacetonate; potassium tert-butylate; oxygen in toluene T=110°C; 2 h; Reagent/catalyst;
参考文献
Shen, Yan; Chen, Jiuxi; Liu, Miaochang; Ding, Jinchang; Gao, Wenxia; Huang, Xiaobo; Wu, Huayue
Chemical Communications, 2014 , vol. 50, # 33 p. 4292 - 4295
反应条件
sodium carbonate; palladium on activated charcoal in ethanol; water T=20°C; Suzuki-Miyaura cross-coupling; 3 h;
参考文献
Kitamura, Yoshiaki; Sakurai, Ai; Udzu, Takahiro; Maegawa, Tomohiro; Monguchi, Yasunari; Sajiki, Hironao
Tetrahedron, 2007 , vol. 63, # 43 p. 10596 - 10602
反应条件
bis(1,5-cyclooctadiene)nickel (0); cesium fluoride; tri-cyclo-hexyl-phosphine in toluene T=120°C; Suzuki-Miyaura coupling; 12 h;
参考文献
Tobisu, Mamoru; Shimasaki, Toshiaki; Chatani, Naoto
Angewandte Chemie - International Edition, 2008 , vol. 47, # 26 p. 4866 - 4869
反应条件
bis(1,5-cyclooctadiene)nickel (0); potassium phosphate; tri-cyclo-hexyl-phosphine in tetrahydrofuran T=25°C; 12 h; Inert atmosphere;
参考文献
Leowanawat, Pawaret; Zhang, Na; Percec, Virgil
Journal of Organic Chemistry, 2012 , vol. 77, # 2 p. 1018 - 1025
反应条件
bis(1,5-cyclooctadiene)nickel (0); potassium phosphate; tri-cyclo-hexyl-phosphine in tetrahydrofuran T=25°C; 12 h; Inert atmosphere;
参考文献
Leowanawat, Pawaret; Zhang, Na; Percec, Virgil
Journal of Organic Chemistry, 2012 , vol. 77, # 2 p. 1018 - 1025
反应条件
bis(1,5-cyclooctadiene)nickel (0); potassium phosphate; tri-cyclo-hexyl-phosphine in tetrahydrofuran T=25°C; 48 h; Inert atmosphere;
参考文献
Leowanawat, Pawaret; Zhang, Na; Percec, Virgil
Journal of Organic Chemistry, 2012 , vol. 77, # 2 p. 1018 - 1025
反应条件
bis(1,5-cyclooctadiene)nickel (0); C{N(2,6-iPr2C6H3)CH}2 in benzene-d6 T=25°C; Inert atmosphere; Kinetics; Concentration;
参考文献
Bouffard, Jean; Itami, Kenichiro
Organic Letters, 2009 , vol. 11, # 19 p. 4410 - 4413
反应条件
1: phenylboronic acid neopentylglycol ester With bis(1,5-cyclooctadiene)nickel (0); Ipr.HCl; cesium fluoride in 1,4-dioxane; toluene T=20°C; 0.5 h; Inert atmosphere; 2: 2-methyl-propan-1-ol With chlorobenzene in 1,4-dioxane; toluene T=60°C; Inert atmosphere;
参考文献
Angewandte Chemie - International Edition, , vol. 50, # 31 p. 7022 - 7026
反应条件
1: phenylboronic acid neopentylglycol ester With bis(1,5-cyclooctadiene)nickel (0); Ipr.HCl; cesium fluoride in 1,4-dioxane; toluene T=20°C; 0.5 h; Inert atmosphere; 2: isobutyraldehyde With chlorobenzene in 1,4-dioxane; toluene T=60°C; 12 h; Inert atmosphere;
参考文献
Angewandte Chemie - International Edition, , vol. 50, # 31 p. 7022 - 7026
