sodium t-butanolate; palladium diacetate; CyPF-t-Bu in ethylene glycol dimethyl ether T=60°C; 48 h;

sodium t-butanolate; palladium diacetate; CyPF-t-Bu in ethylene glycol dimethyl ether T=100°C; 24 h;

1: 1-(iodo)-4-methylbenzene With potassium phosphate; copper(l) iodide; lithium amide in N,N-dimethyl-formamide T=130°C; 6 h; Inert atmosphere; 2: 2-bromo-pyridine in N,N-dimethyl-formamide T=130°C; 18 h; Inert atmosphere; chemoselective reaction;

(C5H5)Fe(C5H3C(CH3)NC6H4CH3)PdCl(CN2(C6H3(CH(CH3)2)2)2C2H2); potassium tert-butylate in 1,4-dioxane T=110°C; Buchwald-Hartwig Coupling; 6 h; Inert atmosphereSchlenk technique;

pyridine; copper diacetate; 4 A molecular sieve in dichloromethane T=20°C; Arylation; 48 h;

1,1'-bis-(diphenylphosphino)ferrocene; [Ni(OPh)3]2(dppf); sodium t-butanolate in toluene T=100°C; 18 h; Schlenk techniqueInert atmosphere;