in acetic acid T=100°C; kinetic isotope effects (kH/kD) at α (D2) and γ (D9), and k12/k14 atα, β, and γ, other arenesulfonates; Product distributionRate constant;
参考文献
Ando,T.; Yamataka,H.; Morisaki,H.
Journal of the American Chemical Society, 1981 , vol. 103, p. 430
in trifluoroacetic acid T=65°C; kinetic isotope effects (kH/kD) at α (D2) and γ (D9), and k12/k14 atα, β, and γ, other arenesulfonates; Product distributionRate constant;
参考文献
Ando,T.; Yamataka,H.; Morisaki,H.
Journal of the American Chemical Society, 1981 , vol. 103, p. 430
water in benzene-d6 treating an equimolar mixture of the starting scandocenes with varying amounts of 2-butyne in a sealed NMR tube, cleaving the intermediates in situ with water;
参考文献
Cotter, W. Donald; Bercaw, John E.
Journal of Organometallic Chemistry, 1991 , vol. 417, # 1/2 p. C1 - C6