2,3-二甲基-1,3-丁二烯合成路线 （共 777 条）
反应条件
chloro-trimethyl-silane T=20°C; Inert atmosphere;
参考文献
Zyk; Gavrilova, A. Yu.; Mukhina; Bondarenko; Zefirov
Russian Chemical Bulletin, 2008 , vol. 57, # 12 p. 2572 - 2578
反应条件
1: 2,3-dimethyl-buta-1,3-diene With lithium in tetrahydrofuran T=0 - 20°C; Inert atmosphere; 2: chloro-trimethyl-silane in tetrahydrofuran T=0 - 20°C; Inert atmosphere;
参考文献
Aouf, Chahinez; El Abed, Douniazad; Giorgi, Michel; Santelli, Maurice
Tetrahedron, 2009 , vol. 65, # 28 p. 5563 - 5570
反应条件
2: (dehydrogenation) 3: Al, HgCl2, cyclohexanol View Scheme
参考文献
Gaylord,N.G.; Stepan,V.
Collection of Czechoslovak Chemical Communications, 1974 , vol. 39, p. 1700 - 1710
参考文献
Belzner, Johannes; Dehnert, Uwe; Schaer, Dirk; Rohde, Bernhard; Mueller, Peter; Uson, Isabel
Journal of Organometalic Chemistry, 2002 , vol. 649, # 1 p. 25 - 42
反应条件
in neat (no solvent) Irradiation (UV/VIS); Ge deriv. and a large excess of organic reagent irradiating in a quartztube for 4 h then concg. in vacuo; identified by high-pressure chromy. and NMR spectra;
参考文献
Journal of Organometallic Chemistry, , vol. 264, # 1-2 p. 193 - 206
反应条件
in neat (no solvent) Ge deriv. heating with a large excess of organic reagent in a sealed tube at 150°C for 6 h, concg. in vacuo; identified by high-pressure chromy. and NMR spectra;
参考文献
Journal of Organometallic Chemistry, , vol. 264, # 1-2 p. 193 - 206
反应条件
in neat (no solvent) Ge deriv. heating with a large excess of organic reagent in a sealed tube at 150°C for 5 h, concg. in vacuo; identified by high-pressure chromy. and NMR spectra;
参考文献
Journal of Organometallic Chemistry, , vol. 264, # 1-2 p. 193 - 206
反应条件
in neat (no solvent) Irradiation (UV/VIS); Ge deriv. and a large excess of organic reagent irradiating in a quartztube for 4 h then concg. in vacuo; identified by high-pressure chromy. and NMR spectra;
参考文献
Journal of Organometallic Chemistry, , vol. 264, # 1-2 p. 193 - 206
反应条件
in neat (no solvent) Irradiation (UV/VIS); Ge deriv. and a large excess of organic reagent irradiating in a quartztube for 4 h then concg. in vacuo; identified by high-pressure chromy. and NMR spectra;
参考文献
Journal of Organometallic Chemistry, , vol. 264, # 1-2 p. 193 - 206
反应条件
T=450°C; P=0.001 Torr; Further byproducts given;
参考文献
Kwak, Young-Woo; Lee, Kyung-Koo
Journal of Organometallic Chemistry, 1997 , vol. 542, # 2 p. 219 - 225
