2,3-二甲基-1,3-丁二烯合成路线 （共 777 条）
反应条件
in cyclohexane
Irradiation (UV/VIS); irradiation of catenate in cyclohexane containing an excess of 2,3-dimethylbutadiene with a 110 W low-pressure Hg arc lamp at room temp. under Ar for 1-4 h, further products; identification by GC and GC-MS;
参考文献
Mochida, Kunio; Kikkawa, Haruhiko; Nakadaira, Yasuhiro
Journal of Organometallic Chemistry, 1991 , vol. 412, # 1.2 p. 9 - 19
反应条件
in cyclohexane
Irradiation (UV/VIS); irradiation of catenate in cyclohexane containing an excess of 2,3-dimethylbutadiene with a 110 W low pressure Hg arc lamp at room temp. under Ar for 1-4 h, further products; identification by GC and GC-MS;
参考文献
Mochida, Kunio; Kikkawa, Haruhiko; Nakadaira, Yasuhiro
Journal of Organometallic Chemistry, 1991 , vol. 412, # 1.2 p. 9 - 19
反应条件
in water
T=310°C; 0.5 h;
参考文献
Korzenski, Michael B.; Kolis, Joseph W.
Tetrahedron Letters, 1997 , vol. 38, # 32 p. 5611 - 5614
反应条件
1: neat (no solvent) / |Inert atmosphere; |Schlenk technique
2: manganese(IV) oxide / toluene / 3 h / |Inert atmosphere; |Schlenk technique
View Scheme
参考文献
Sullivan, David J.; Clerac, Rodolphe; Jennings, Michael; Lough, Alan J.; Preuss, Kathryn E.
Chemical Communications, 2012 , vol. 48, # 89 p. 10963 - 10965
参考文献
Carreno, M. Carmen; Ruano, Jose L. Garcia; Urbano, Antonio
Tetrahedron Letters, 1989 , vol. 30, # 30 p. 4003 - 4006
反应条件
in hexane
Irradiation (UV/VIS); further products; (Ar); SiGe compd. in hexane was mixed with 1,3-dimethyl-2,3-butadiene; photolyzed for 1 h in quartz sealed tubes; GC, GC/MS, PMR monitoring; not isolated;
参考文献
Leigh, William J.; Toltl, Nicholas P.; Apodaca, Paula; Castruita, Madeli; Pannell, Keith H.
Organometallics, 2000 , vol. 19, # 16 p. 3232 - 3241
反应条件
lithium tert-butylate
1. 0 deg C, THF; Yield given. Multistep reaction;
参考文献
Bates, Robert B.; Gordon, Bernard; Highsmith, Thomas K.; White, James J.
Journal of Organic Chemistry, 1984 , vol. 49, # 16 p. 2981 - 2987
反应条件
ethyl vinyl ether in acetonitrile
72 h; Ambient temperature;
参考文献
Cano, Pilar; Farina, Francisco; Parellada, M. Dolores; Pascual, Conrado; Prados, Pilar
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1986 , p. 1923 - 1928
反应条件
hydroquinone in acetonitrile
24 h; Heating;
参考文献
Cano, Pilar; Farina, Francisco; Parellada, M. Dolores; Pascual, Conrado; Prados, Pilar
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1986 , p. 1923 - 1928
反应条件
sulfur trioxide; 1,2-dichloro-ethane
参考文献
Bordwell et al.
Journal of the American Chemical Society, 1959 , vol. 81, p. 2002,2006
