2,3-二甲基-1,3-丁二烯合成路线 （共 777 条）
反应条件
in solid matrix
Irradiation (UV/VIS); under Ar at 77K for 10 min in 3-methylpentane matrix; warmed to melt; reaction monitored by UV-spectroscopy; GLC-mass spectrometry;
参考文献
Tsumuraya, Takeshi; Sadao, Sato; Ando, Wataru
Organometallics, 1989 , vol. 8, p. 161 - 167
反应条件
in tetrahydrofuran
THF soln. of Ge complex heated to 70°C in sealed tube;
参考文献
Rupar, Paul A.; Jennings, Michael C.; Ragogna, Paul J.; Baines, Kim M.
Organometallics, 2007 , vol. 26, # 17 p. 4109 - 4111
反应条件
in hexane
T=-70°C; 20 h; UV-irradiation;
参考文献
Hurni, Krysten L.; Baines, Kim M.
Canadian Journal of Chemistry, 2007 , vol. 85, # 10 p. 668 - 674
反应条件
in hexane
byproducts: Si2(CH3)6, C6H3(CH3)3, (CH3)3SiC6H2(CH3)3; Irradiation (UV/VIS); (Ar); photolysis of hexanes soln. of germanium compd. and dimethylbutadiene at -70°C for 24 h; evapn., chromy. (silica gel, hexanes) to isolate dimesitylgermacyclopentene deriv., thin layer chromy. (silica gel. hexanes), NMR and MAS;
参考文献
Hurni, Krysten L.; Baines, Kim M.
Canadian Journal of Chemistry, 2007 , vol. 85, # 10 p. 668 - 674
反应条件
in toluene
T=95 - 97°C; 20 h;
参考文献
Baldwin, Jack E.; Lopez, R. C. Gerald
Journal of the Chemical Society, Chemical Communications, 1982 , # 18 p. 1029 - 1030
反应条件
in toluene
T=129 - 131°C; 24 h; sealed tube;
参考文献
Baldwin, Jack E.; Lopez, Gerald R. C.
Tetrahedron, 1983 , vol. 39, # 9 p. 1487 - 1498
参考文献
Maier, G.; Reisenauer, H. P.; Schoettler, K.; Wessolek-Kraus, U.
Journal of Organometallic Chemistry, 1989 , vol. 366, p. 25 - 38
反应条件
T=-75°C; 8 h; Irradiation;
参考文献
Maier, G.; Reisenauer, H. P.; Schoettler, K.; Wessolek-Kraus, U.
Journal of Organometallic Chemistry, 1989 , vol. 366, p. 25 - 38
反应条件
T=370°C; 0.00194444 h;
参考文献
Maier, G.; Reisenauer, H. P.; Schoettler, K.; Wessolek-Kraus, U.
Journal of Organometallic Chemistry, 1989 , vol. 366, p. 25 - 38
参考文献
Barton, Thomas J.; Burns, Gary T.
Tetrahedron Letters, 1983 , vol. 24, # 2 p. 159 - 162
