2,3-二甲基-1,3-丁二烯合成路线 （共 777 条）
反应条件
in neat (no solvent)
heating in sealed tube, 150°C for 2h;;
参考文献
Barrau, Jacques; Rima, Ghassoub; Cassano, Valerie
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1992 , vol. 22, p. 1431 - 1444
反应条件
in neat (no solvent)
a mixt. of digermadithiane and CH2=CMeCMe=CH2 was heated in a sealed tube at 200°C for 4 h; analyzed by GC;
参考文献
Barrau, J.; Amine, M. El; Rima, G.; Satge, J.
Journal of Organometallic Chemistry, 1984 , vol. 277, # 3 p. 323 - 334
反应条件
in hexane
byproducts: (C6H5)3SiCH3, C6H5SiH; Irradiation (UV/VIS); (Ar); SiGe compd. in hexane was mixed with 2,3-dimethyl-1,3-butadiene; photolyzed for 1 h in quartz sealed tubes; GC, GC/MS, PMR monitoring; solvent was evapd.; dissolved in pentane; isolated by semipreparative GC;
参考文献
Leigh, William J.; Toltl, Nicholas P.; Apodaca, Paula; Castruita, Madeli; Pannell, Keith H.
Organometallics, 2000 , vol. 19, # 16 p. 3232 - 3241
反应条件
in cyclohexane
Ar atmosphere, large excess butadiene, photolysis (low-pressure Hg lamp, 253.7 nm, room temp., 4 h);
参考文献
Tomoda, Shuji; Shimoda, Masakatsu; Takeuchi, Yoshito; Kajii, Yoshizumi; Obi, Kinichi; et al.
Journal of the Chemical Society, Chemical Communications, 1988 , p. 910 - 912
反应条件
in cyclohexane
Irradiation (UV/VIS); irradiation of catenate in cyclohexane containing an excess of 2,3-dimethylbutadiene with a 110 W low-pressure Hg arc lamp at room temp. under Ar for 1-4 h; identification by GC and GC-MS;
参考文献
Mochida, Kunio; Kikkawa, Haruhiko; Nakadaira, Yasuhiro
Journal of Organometallic Chemistry, 1991 , vol. 412, # 1.2 p. 9 - 19
反应条件
in cyclohexane
Kinetics; Irradiation (UV/VIS); generation of (CH3)2Ge by photolysis of ((CH3)2Ge)6 in C6H12 at 293K in presence of a large excess of diene;;
参考文献
Mochida, Kunio; Kanno, Naoko; Kato, Ryuji; Kotani, Masahiro; Yamauchi, Seigo; et al.
Journal of Organometallic Chemistry, 1991 , vol. 415, # 2 p. 191 - 201
反应条件
in cyclohexane
Irradiation (UV/VIS); 20 molar equivalents of diene, 110-W low pressure Hg arc lamp (254nm, spiral type), 293K, 30min, under Ar;; detn. by GLC and GC-MS;;
参考文献
Mochida, Kunio; Kanno, Naoko; Kato, Ryuji; Kotani, Masahiro; Yamauchi, Seigo; et al.
Journal of Organometallic Chemistry, 1991 , vol. 415, # 2 p. 191 - 201
反应条件
in cyclohexane
Irradiation (UV/VIS); Irradn. with a 110 W low-pressure Hg arc lamp at room temp. under Ar for 10 h.; GC-MS.;
参考文献
Mochida, Kunio; Kikkawa, Haruhiko; Nakadaira, Yasuhiro
Bulletin of the Chemical Society of Japan, 1991 , vol. 64, # 9 p. 2772 - 2777
反应条件
in hexane
Irradiation (UV/VIS); further products; (Ar); SiGe compd. in hexane was mixed with 1,3-dimethyl-2,3-butadiene; photolyzed for 1 h in quartz sealed tubes; GC, GC/MS, PMR monitoring; not isolated;
参考文献
Leigh, William J.; Toltl, Nicholas P.; Apodaca, Paula; Castruita, Madeli; Pannell, Keith H.
Organometallics, 2000 , vol. 19, # 16 p. 3232 - 3241
反应条件
in cyclohexane
Irradiation (UV/VIS); Hg-arc lamp; 85 percent conversion was observed;
参考文献
Mochida, Kunio; Ohto, Junichi; Masuda, Matsuri; Nanjo, Masato; Arii, Hidekazu; Nakadaira, Yasuhiro
Chemistry Letters, 2008 , vol. 37, # 1 p. 20 - 21
