2-(烯丙基硫代)苯并咪唑合成路线 （共 17 条）
反应条件
sodium hydroxide; tetrabutylammomium bromide T=45 - 55°C; Rearrangement; substitution; disproportionation; allylation; 18 h; Further byproducts given;
参考文献
Chemistry of Heterocyclic Compounds, , vol. 36, # 2 p. 201 - 206
反应条件
bromine; sodium acetate in N,N-dimethyl-formamide
T=80°C; 5 h;
参考文献
Korotkikh, N. I.; Raenko, G. F.; Shvaika, O. P.
Chemistry of Heterocyclic Compounds (New York, NY, United States), 1995 , vol. 31, # 3 p. 359 - 363
Khimiya Geterotsiklicheskikh Soedinenii, 1995 , # 3 p. 410 - 415
反应条件
1: 57 percent / bromine / acetic acid / 20 °C
2: 68 percent / H2O; propan-2-ol / 15 h / Heating
3: 89 percent / sodium acetate / H2O; CHCl3 / 1 h
4: KOH / methanol / 6 h / Heating
View Scheme
参考文献
Korotkikh; Raenko; Aslanov
Russian Journal of Organic Chemistry, 1996 , vol. 32, # 4 p. 610 - 618
反应条件
bromine; sodium acetate in N,N-dimethyl-formamide
T=80°C; 5 h; Title compound not separated from byproducts;
参考文献
Korotkikh, N. I.; Raenko, G. F.; Shvaika, O. P.
Chemistry of Heterocyclic Compounds (New York, NY, United States), 1995 , vol. 31, # 3 p. 359 - 363
Khimiya Geterotsiklicheskikh Soedinenii, 1995 , # 3 p. 410 - 415
反应条件
bromine; sodium acetate in N,N-dimethyl-formamide
T=80°C; 5 h;
参考文献
Korotkikh, N. I.; Raenko, G. F.; Shvaika, O. P.
Chemistry of Heterocyclic Compounds (New York, NY, United States), 1995 , vol. 31, # 3 p. 359 - 363
Khimiya Geterotsiklicheskikh Soedinenii, 1995 , # 3 p. 410 - 415
反应条件
1: 57 percent / bromine / acetic acid / 20 °C
2: 68 percent / H2O; propan-2-ol / 15 h / Heating
3: 89 percent / sodium acetate / H2O; CHCl3 / 1 h
4: KOH / methanol / 6 h / Heating
View Scheme
参考文献
Korotkikh; Raenko; Aslanov
Russian Journal of Organic Chemistry, 1996 , vol. 32, # 4 p. 610 - 618
反应条件
bromine; sodium acetate in N,N-dimethyl-formamide
T=80°C; 5 h; Title compound not separated from byproducts;
参考文献
Korotkikh, N. I.; Raenko, G. F.; Shvaika, O. P.
Chemistry of Heterocyclic Compounds (New York, NY, United States), 1995 , vol. 31, # 3 p. 359 - 363
Khimiya Geterotsiklicheskikh Soedinenii, 1995 , # 3 p. 410 - 415
反应条件
T=200°C; Rearrangement; allylation; 2 h;
参考文献
Ramazanova; Tarakanova; Vagabov; Litvinova; Anisimov
Chemistry of Heterocyclic Compounds, 2000 , vol. 36, # 2 p. 201 - 206
反应条件
sodium hydroxide; tetrabutylammomium bromide
T=45 - 55°C; Rearrangement; substitution; disproportionation; allylation; 18 h; Further byproducts given;
参考文献
Ramazanova; Tarakanova; Vagabov; Litvinova; Anisimov
Chemistry of Heterocyclic Compounds, 2000 , vol. 36, # 2 p. 201 - 206
反应条件
reconstructed hydrotalcite in ethanol
T=70°C; 3 h; Microwave irradiationCooling; Reagent/catalyst;
参考文献
Cruz-Gonzalez, Deysi Y.; Gonzalez-Olvera, Rodrigo; Angeles-Beltran, Deyanira; Negron-Silva, Guillermo E.; Santillan, Rosa
Synthesis (Germany), 2013 , vol. 45, # 23 p. 3281 - 3287
