(1S,4R)-4-(硝基甲基)-2-环戊烯-1-基乙酸酯合成路线 （共 4 条）
反应条件
(S,S)-DACH-phenyl Trost ligand; BSA; tris(dibenzylideneacetone)dipalladium(0) chloroform complex in dichloromethane
参考文献
Trost, Barry M.; Surivet, Jean-Philippe
Angewandte Chemie - International Edition, 2000 , vol. 39, # 17 p. 3122 - 3124
反应条件
pyridine in dichloromethane
T=0 - 20°C;
参考文献
Rajappan, Vasathakumar P; Yin, Xueqiang; Schneller, Stewart W
Tetrahedron, 2002 , vol. 58, # 49 p. 9889 - 9895
反应条件
sodium hydroxide; Pseudomonas cepacia lipase in phosphate buffer; acetone
pH=7.0 - 7.2;
参考文献
Rajappan, Vasathakumar P; Yin, Xueqiang; Schneller, Stewart W
Tetrahedron, 2002 , vol. 58, # 49 p. 9889 - 9895
反应条件
1: 45 percent / Pseudomonas cepacia lipase; NaOH / aq. phosphate buffer; acetone / pH 7.0 - 7.2
2: 90 percent / pyridine / CH2Cl2 / 0 - 20 °C
View Scheme
参考文献
Rajappan, Vasathakumar P; Yin, Xueqiang; Schneller, Stewart W
Tetrahedron, 2002 , vol. 58, # 49 p. 9889 - 9895
