4,4-二硝基-2,2-联吡啶 N,N-二氧化物合成路线 （共 17 条）
反应条件
phosphorus trichoride in acetonitrile 1) reflux, 1.75 h, 2) room temperature, overnight;
参考文献
Journal of Organic Chemistry, , vol. 48, # 3 p. 283 - 289
反应条件
acetic acid; acetyl chloride
T=100°C; 2 h;
参考文献
Anderson, Susan; Constable, Edwin C.; Seddon, Kenneth R.; Turp, Janet E.; Baggott, James E.; Pilling, Michael J.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1985 , p. 2247 - 2262
反应条件
acetyl-bromide in acetic acid
T=100°C; 4 h;
参考文献
Han, Won-Sik; Han, Jung-Kyu; Kim, Hyun-Young; Choi, Mi Jin; Kang, Yong-Soo; Pac, Chyongjin; Kang, Sang Ook
Inorganic Chemistry, 2011 , vol. 50, # 8 p. 3271 - 3280
参考文献
Maerker; Case
Journal of the American Chemical Society, 1958 , vol. 80, p. 2745,2747
反应条件
1: acetic acid; acetyl chloride / 4 h / 100 °C / |Inert atmosphere; |Schlenk technique
2: trichlorophosphate / chloroform / 19 h / |Inert atmosphere; |Reflux; |Schlenk technique
3: 90 h / 200 - 220 °C / |Sealed tube; |Inert atmosphere; |Schlenk technique
View Scheme
参考文献
Ladouceur, Sebastien; Swanick, Kalen N.; Gallagher-Duval, Shawn; Ding, Zhifeng; Zysman-Colman, Eli
European Journal of Inorganic Chemistry, 2013 , # 30 p. 5329 - 5343
反应条件
nitrobenzene
Behandeln des Reaktionsprodukts mit PCl3 in CHCl3;
参考文献
Maerker; Case
Journal of the American Chemical Society, 1958 , vol. 80, p. 2745,2747
反应条件
1.1: AcBr / acetic acid / Heating
2.1: PBr3 / CHCl3
3.1: tetrakis(triphenylphosphine) Pd(0); aq. potassium carbonate / dimethylformamide / 24 h / 85 - 95 °C
3.2: 30.4 percent / dimethylformamide / 5 h / 115 °C
View Scheme
参考文献
Carlson, Brenden; Phelan, Gregory D.; Kaminsky, Werner; Dalton, Larry; Jiang, Xuezhong; Liu, Sen; Jen, Alex K.-Y.
Journal of the American Chemical Society, 2002 , vol. 124, # 47 p. 14162 - 14172
