1-(2-硝基苯基)-1,2-乙二醇合成路线 （共 15 条）
反应条件
1: 88 percent / sodium borohydride / dioxane; H2O / 1.) 2 h at 5 deg C; 2.) 30 min room temperature
2: 78 percent / 10 percent aq potassium carbonate / dioxane / 17 h / Heating; in the dark
View Scheme
参考文献
Gravel, D.; Herbert, J.; Thoraval, D.
Canadian Journal of Chemistry, 1983 , vol. 61, p. 400 - 410
反应条件
dihydrogen peroxide; lipase [PSLG6] in water
Heating;
参考文献
Sarma, Kuladip; Borthakur, Naleen; Goswami, Amrit
Tetrahedron Letters, 2007 , vol. 48, # 38 p. 6776 - 6778
反应条件
1: 78 percent / NaOH / H2O
2: 7 percent / 5percent-ig. HClO4 / tetrahydrofuran / 20 h / Ambient temperature
View Scheme
参考文献
Wierenga, Wendell; Harrison, Allen W.; Evans, Bruce R.; Chidester, Connie G.
Journal of Organic Chemistry, 1984 , vol. 49, # 3 p. 438 - 442
反应条件
β-CDB; hydrogen; Rh on carbon
1.) H2O, 25 deg C, 8 h, 2.) MeOH; Yield given. Multistep reaction;
参考文献
Bhat, Shridhar; Chandrasekaran, Srinivasan
Tetrahedron Letters, 1996 , vol. 37, # 20 p. 3581 - 3584
反应条件
1: 14 percent / diethyl ether / 1.) 0 deg C 1 h: 2.) 3 h room temperature
2: 68 percent / bromine / dioxane / 2 h
3: 88 percent / sodium borohydride / dioxane; H2O / 1.) 2 h at 5 deg C; 2.) 30 min room temperature
4: 78 percent / 10 percent aq potassium carbonate / dioxane / 17 h / Heating; in the dark
View Scheme
参考文献
Gravel, D.; Herbert, J.; Thoraval, D.
Canadian Journal of Chemistry, 1983 , vol. 61, p. 400 - 410
