1-(1,1':2',1''-三联苯-4-基)乙酮合成路线 （共 11 条）
反应条件
potassium carbonate in ethanol; water
T=20°C; Suzuki-Miyaura reaction; 2 h; Inert atmosphere;
参考文献
Hagiwara, Hisahiro; Sato, Kota; Hoshi, Takashi; Suzuki, Toshio
Synlett, 2011 , # 17 p. 2545 - 2550
反应条件
potassium phosphate; C58H72N2O4P2Pd2 in tert-butyl alcohol
T=110°C; Suzuki-Miyaura cross-coupling; 3 h; Inert atmosphere;
参考文献
So, Chau Ming; Lau, Chak Po; Kwong, Fuk Yee
Angewandte Chemie - International Edition, 2008 , vol. 47, # 42 p. 8059 - 8063
反应条件
Pd0(tris(tert-butyl)phosphine)2; water; caesium carbonate in ethylene glycol dimethyl ether
T=80°C; Suzuki-Miyaura cross-coupling reaction; 22 h; Inert atmosphere;
参考文献
Yoshida, Hiroto; Okada, Kengo; Kawashima, Shota; Tanino, Kenji; Ohshita, Joji
Chemical Communications, 2010 , vol. 46, # 10 p. 1763 - 1765
反应条件
potassium carbonate in ethanol; water
T=60°C; Suzuki-Miyaura reaction; 2 h; in air;
参考文献
Hagiwara, Hisahiro; Sasaki, Hirokazu; Tsubokawa, Norio; Hoshi, Takashi; Suzuki, Toshio; Tsuda, Tetsuya; Kuwabata, Susumu
Synlett, 2010 , # 13 p. 1990 - 1996
反应条件
dicyclohexyl(2′,6′-dimethoxybiphenyl-2-yl)phosphine; palladium diacetate in tetrahydrofuran; water
T=60°C; Suzuki-Miyaura cross-coupling; 21 h;
参考文献
Antelo Miguez, Jose M.; Adrio, Luis Angel; Sousa-Pedrares, Antonio; Vila, Jose M.; Hii, King Kuok
Journal of Organic Chemistry, 2007 , vol. 72, # 20 p. 7771 - 7774
反应条件
1: 100 percent / K3PO4 / Pd(OAc)2 / dimethylformamide; H2O / 3 h / 20 °C
2: (2',6'-dimethoxybiphenyl-2-yl)dicyclohexylphosphine / Pd3(OAc)6 / tetrahydrofuran; H2O / 21 h / 60 °C
View Scheme
参考文献
Antelo Miguez, Jose M.; Adrio, Luis Angel; Sousa-Pedrares, Antonio; Vila, Jose M.; Hii, King Kuok
Journal of Organic Chemistry, 2007 , vol. 72, # 20 p. 7771 - 7774
反应条件
1: 100 percent / K3PO4 / Pd(OAc)2 / dimethylformamide; H2O / 3 h / 20 °C
2: (2',6'-dimethoxybiphenyl-2-yl)dicyclohexylphosphine / Pd3(OAc)6 / tetrahydrofuran; H2O / 21 h / 60 °C
View Scheme
参考文献
Antelo Miguez, Jose M.; Adrio, Luis Angel; Sousa-Pedrares, Antonio; Vila, Jose M.; Hii, King Kuok
Journal of Organic Chemistry, 2007 , vol. 72, # 20 p. 7771 - 7774
反应条件
aluminium trichloride; 1,2-dichloro-ethane
参考文献
Allen; Burness
Journal of Organic Chemistry, 1949 , vol. 14, p. 163,167
Full Text Show Details
Allen; Pingert
Journal of the American Chemical Society, 1942 , vol. 64, p. 2639,2641
反应条件
T=220°C; Eintragen von aktiviertem Kupfer-Pulver;
参考文献
Allen; Pingert
Journal of the American Chemical Society, 1942 , vol. 64, p. 2639,2641
参考文献
Allen; Pingert
Journal of the American Chemical Society, 1942 , vol. 64, p. 2639,2641
