1,10-phenanthroline; tri-ruthenium(0)dodecacarbonyl
T=120°C; P=30400 Torr; 10 h; Yields of byproduct given. Title compound not separated from byproducts;
1,10-phenanthroline; tri-ruthenium(0)dodecacarbonyl
T=120°C; P=30400 Torr; 10 h; Yields of byproduct given. Title compound not separated from byproducts;
carbon monoxide; butyric acid sodium salt in neat (no solvent)
mixt. of PdCl(C3H5), HCO2Me, Na butyrate (as nucleophile) stirred at room temp. for 30 min, addn. of CO, react. time 2 h; react. mixt. filtered, colourless liquid analysed by GLC;
参考文献
Keim; Becker; Kraneburg; Greven
Journal of molecular catalysis, 1989 , vol. 54, # 1 p. 37 - 43
carbon monoxide; butyric acid sodium salt in neat (no solvent)
mixt. of PdCl(C3H5), MeOH, Na butyrate (as nucleophile) stirred at room temp. for 30 min, addn. of CO, react. time 2 h; react. mixt. filtered, colourless liquid analysed by GLC;
参考文献
Keim; Becker; Kraneburg; Greven
Journal of molecular catalysis, 1989 , vol. 54, # 1 p. 37 - 43
