deuterium; platinum (111) single crystal in gaseous matrix
T=59.9°C; P=110 Torr; variation of temperature and partial pressures; ΔH(excit.); isotope effect; rate of ethylene deuterium exchange; KineticsMechanismProduct distribution;
参考文献
Zaera, F.; Somorjai, G. A.
Journal of the American Chemical Society, 1984 , vol. 106, # 8 p. 2288 - 2293
deuterium; platinum on silica; PtNa
T=-26.1°C; P=9.8 Torr; activation energy; different amounts of Na (Na/Pt from 0.00 to 6.1); Thermodynamic dataKinetics;
参考文献
Yoshitake, Hideaki; Iwasawa, Yasuhiro
Journal of Physical Chemistry, 1991 , vol. 95, # 19 p. 7368 - 7372
H2 or D2; zinc oxide
T=-26.1 - 20.9°C; free energy of adsorption, hydrogenation, deuteration and exchange with deuterium, poisoning of the catalyst by CO2; Rate constant;
参考文献
Brown, Ronald; Kemball, Charles; Taylor, Duncan
Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, 1983 , vol. 79, p. 2899 - 2914
