4,4’-二硝基-2-联苯胺合成路线 （共 17 条）
反应条件
1.1: tin(IV) chloride / nitrobenzene 2.1: nitrobenzene / 17.5 h / 20 - 165 °C 3.1: sulfuric acid; iron / ethanol; water / 1.5 h / Reflux 3.2: 25 °C View Scheme
参考文献
Osadchii; Shubin; Kozlova; Varlamenko; Filipenko; Boyarskikh
Russian Journal of Applied Chemistry, 2011 , vol. 84, # 9 p. 1541 - 1548
反应条件
sulfuric acid Diazotization.Behandlung der Diazoniumsalz-Loesung mit wss. H3PO2 in der Waerme;
参考文献
Finzi; Bellavita
Gazzetta Chimica Italiana, 1938 , vol. 68, p. 77,84
Full Text Show Details
Cymerman; Short
Journal of the Chemical Society, 1949 , p. 703,706,707
Full Text Show Details
Ritchie
Journal and Proceedings of the Royal Society of New South Wales, 1944 , vol. 78, p. 164,167
反应条件
1: chlorobenzene / 1.5 h / Heating
2: POCl3 / nitrobenzene / 2 h / Heating
View Scheme
参考文献
Letsinger, Robert L.; Schott, Margaret E.
Journal of the American Chemical Society, 1981 , vol. 103, # 24 p. 7394 - 7396
反应条件
1: tin(IV) chloride / nitrobenzene
2: nitrobenzene / 17.5 h / 20 - 165 °C
View Scheme
参考文献
Osadchii; Shubin; Kozlova; Varlamenko; Filipenko; Boyarskikh
Russian Journal of Applied Chemistry, 2011 , vol. 84, # 9 p. 1541 - 1548
反应条件
1.1: sodium nitrite; sulfuric acid; acetic acid / 2 h / 5 - 10 °C
1.2: 80.1 percent / sodium azide / H2O / 25 h / 0 - 20 °C
2.1: 86 percent / kerosene / 1 h / Heating
3.1: 67 percent / tin(II) chloride; acetic acid; hydrochloric acid / 24 h / Heating
4.1: sodium nitrite; aq. HCl / 2 h / 0 °C
4.2: potassium iodide / H2O / 24 h / 20 °C
5.1: 1.57 g / NaOH / benzyltrimethylammonium chloride / dimethylsulfoxide; H2O / 3 h / 80 °C
6.1: n-BuLi / tetrahydrofuran; hexane / -78 - 0 °C
6.2: 42.4 percent / tetrahydrofuran; hexane / -78 - 20 °C
View Scheme
参考文献
Pan, Xiaoyong; Liu, Shouping; Chan, Hardy S.O.; Ng, Siu-Choon
Macromolecules, 2005 , vol. 38, # 18 p. 7629 - 7635
反应条件
1: tin(IV) chloride / nitrobenzene
2: NH2NH2•xH2O / ethanol / 1 h / 75 °C
3: pyridine
View Scheme
参考文献
Osadchii; Shubin; Kozlova; Varlamenko; Filipenko; Boyarskikh
Russian Journal of Applied Chemistry, 2011 , vol. 84, # 9 p. 1541 - 1548
反应条件
1.1: sodium nitrite; sulfuric acid; acetic acid / 2 h / 5 - 10 °C
1.2: 80.1 percent / sodium azide / H2O / 25 h / 0 - 20 °C
2.1: 86 percent / kerosene / 1 h / Heating
3.1: 67 percent / tin(II) chloride; acetic acid; hydrochloric acid / 24 h / Heating
View Scheme
参考文献
Baycan Koyuncu, Fatma; Koyuncu, Sermet; Ozdemir, Eyup
Organic Electronics: physics, materials, applications, 2011 , vol. 12, # 10 p. 1701 - 1710
