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结构式
乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
51870-64-5
合成路线
(共 16 条)
923595-14-6
→
反应条件
51870-64-5
反应条件
ytterbium trifluoromethanesulfonate; [Pd(dppp)(H2O)2](2+)(OTf(1-))2 in 1,4-dioxane T=80°C; 2 h;
参考文献
Liu, Guixia; Lu, Xiyan
Tetrahedron, 2008 , vol. 64, # 30-31 p. 7324 - 7330
92496-20-3
→
反应条件
51870-64-5
反应条件
silver trifluoromethanesulfonate in dichloromethane T=60°C; 1 h;
参考文献
Arcadi, Antonio; Blesi, Federico; Cacchi, Sandro; Fabrizi, Giancarlo; Goggiamani, Antonella; Marinelli, Fabio
Organic and Biomolecular Chemistry, 2012 , vol. 10, # 48 p. 9700 - 9708
38276-75-4
→
反应条件
51870-64-5
反应条件
air; water; potassium hydrogencarbonate; bis(dibenzylideneacetone)-palladium(0) in dimethyl sulfoxide T=60°C; 72 h;
参考文献
Larock, Richard C.; Wei, Lulin; Hightower, Timothy R.
Synlett, 1998 , # 5 p. 522 - 524
92496-20-3
→
反应条件
51870-64-5
+
92496-19-0
反应条件
platinum (IV)-chloride in 1,4-dioxane T=20°C; 0.0833333 h;
参考文献
Pastine, Stefan J.; Youn, So Won; Sames, Dalibor
Organic Letters, 2003 , vol. 5, # 7 p. 1055 - 1058
1159707-87-5
→
反应条件
51870-64-5
反应条件
Grubb's 2nd generation catalyst in dichloromethane T=20°C; 4 h;
参考文献
Li, Sie-Rong; Chen, Hsing-Ming; Chen, Po-Yuan; Tsai, Jui-Chi; Chen, Liang-Yeu; Wang, Eng-Chi; Huang, Yi-Ting; Wei, Yun-Chen; Lu, Pei-Jung
Journal of the Chinese Chemical Society, 2008 , vol. 55, # 4 p. 923 - 932
→
反应条件
51870-64-5
反应条件
tetrakis(triphenylphosphine) palladium(0); oxygen; copper(l) chloride; lithium tert-butylate in 1,4-dioxane T=70°C;
参考文献
Zhao, Xia; Jing, Jing; Lu, Kui; Zhang, Yan; Wang, Jianbo
Chemical Communications, 2010 , vol. 46, # 10 p. 1724 - 1726
1504-58-1
3-苯基-2-丙炔-1-醇
→
反应条件
51870-64-5
反应条件
1: 65 percent / triphenylphosphine; diethyl azodicarboxylate / tetrahydrofuran / 24 h / 20 °C 2: 57 percent / PtCl4 / dioxane / 0.08 h / 20 °C View Scheme
参考文献
Pastine, Stefan J.; Youn, So Won; Sames, Dalibor
Organic Letters, 2003 , vol. 5, # 7 p. 1055 - 1058
108-95-2
苯酚
→
反应条件
51870-64-5
反应条件
1: 65 percent / triphenylphosphine; diethyl azodicarboxylate / tetrahydrofuran / 24 h / 20 °C 2: 57 percent / PtCl4 / dioxane / 0.08 h / 20 °C View Scheme
参考文献
Pastine, Stefan J.; Youn, So Won; Sames, Dalibor
Organic Letters, 2003 , vol. 5, # 7 p. 1055 - 1058
174617-52-8
+
98-80-6
苯硼酸
→
反应条件
51870-64-5
反应条件
1: 4-trifluoromethylsulfonyloxy-2H-chromene With potassium carbonate; bis(dibenzylideneacetone)-palladium(0) in benzene 0.5 h; 2: 3,4,5-trimethoxyphenylboronic acid in ethanol; benzene Heating;
参考文献
Eguchi, Tetsuya; Hoshino, Yukio; Ayame, Akimi
Bulletin of the Chemical Society of Japan, 2002 , vol. 75, # 3 p. 581 - 585
960-16-7
三丁基苯基锡
+
174617-52-8
→
反应条件
51870-64-5
反应条件
copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); lithium chloride in 1,4-dioxane Stille coupling; Heating;
参考文献
Eguchi, Tetsuya; Hoshino, Yukio; Ayame, Akimi
Bulletin of the Chemical Society of Japan, 2002 , vol. 75, # 3 p. 581 - 585
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