5,6,6A,7-四氢-4H-二苯并[去,G]喹啉合成路线 （共 4 条）
反应条件
1: in methanol; water
T=20°C; 0.5 h;
2: With sodium tetrahydroborate
T=20°C; 1 h; Further stages.;
参考文献
Cuny, Gregory D.
Tetrahedron Letters, 2004 , vol. 45, # 26 p. 5167 - 5170
反应条件
NpH; sodium in ethylene glycol dimethyl ether
T=-56°C;
参考文献
Cuny, Gregory D.
Tetrahedron Letters, 2004 , vol. 45, # 26 p. 5167 - 5170
反应条件
1: 100 percent / 2,6-lutidine / CH2Cl2 / 0.5 h / 0 °C
2: 77 percent / DPPF; Et3N; HCOO2H / Pd(OAc)2 / dimethylformamide / 24 h / 80 °C
3: 89 percent / Na; NpH / 1,2-dimethoxy-ethane / -56 °C
View Scheme
参考文献
Cuny, Gregory D.
Tetrahedron Letters, 2004 , vol. 45, # 26 p. 5167 - 5170
反应条件
1: 77 percent / DPPF; Et3N; HCOO2H / Pd(OAc)2 / dimethylformamide / 24 h / 80 °C
2: 89 percent / Na; NpH / 1,2-dimethoxy-ethane / -56 °C
View Scheme
参考文献
Cuny, Gregory D.
Tetrahedron Letters, 2004 , vol. 45, # 26 p. 5167 - 5170
