2,5-二羟基-3,6-二(4-羟基苯基)-2,5-环己二烯-1,4-二酮合成路线 （共 17 条）
反应条件
zinc bei der Destillation;
参考文献
Justus Liebigs Annalen der Chemie, , vol. 440, p. 33
Justus Liebigs Annalen der Chemie, , vol. 445, p. 160,164
参考文献
Koegl; Postowsky
Justus Liebigs Annalen der Chemie, 1925 , vol. 445, p. 168
参考文献
Koegl; Postowsky
Justus Liebigs Annalen der Chemie, 1925 , vol. 445, p. 168
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Thoerner
Chemische Berichte, 1879 , vol. 12, p. 1632
参考文献
Koegl; Postowsky
Justus Liebigs Annalen der Chemie, 1925 , vol. 445, p. 168
参考文献
Koegl; Postowsky
Justus Liebigs Annalen der Chemie, 1925 , vol. 445, p. 168
Full Text Show Details
Thoerner
Chemische Berichte, 1879 , vol. 12, p. 1632
反应条件
sodium hydride
1.) reflux, THF, 2.) 24 h, 25 deg C, THF; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Besl, Helmut; Bresinsky, Andreas; Geigenmueller, Georg; Herrmann, Rupert; Kilpert, Claus; Steglich, Wolfgang
Liebigs Annalen der Chemie, 1989 , p. 803 - 810
反应条件
hydrogen bromide in acetic acid; acetone
T=50°C; 2 h;
参考文献
Hu, Lin; Gao, Jin-Ming; Liu, Ji-Kai
Helvetica Chimica Acta, 2001 , vol. 84, # 11 p. 3342 - 3349
反应条件
1: (i) NaOEt, EtOH, toluene, (ii) /BRN= 505943/
2: aq. NaBH4 / Pd-C
3: (i) NaNO2, aq. HCl, (ii) /BRN= 1864206/, NaOAc
4: aq. NaOH
5: aq. H2SO4 / acetic acid
View Scheme
参考文献
Edwards,R.L.; Kale,N.
Journal of the Chemical Society, 1964 , p. 4084 - 4085
反应条件
1: aq. NaBH4 / Pd-C
2: (i) NaNO2, aq. HCl, (ii) /BRN= 1864206/, NaOAc
3: aq. NaOH
4: aq. H2SO4 / acetic acid
View Scheme
参考文献
Edwards,R.L.; Kale,N.
Journal of the Chemical Society, 1964 , p. 4084 - 4085
反应条件
sodium hydroxide in methanol
参考文献
Jaegers, Elisabeth; Hillen-Maske, Elisabeth; Schmidt, Holger; Steglich, Wolfgang; Horak, Egon
Zeitschrift fuer Naturforschung, B: Chemical Sciences, 1987 , vol. 42, # 10 p. 1354 - 1360
