2-氯乙氧基-2-乙氧基二乙醇合成路线 （共 57 条）
反应条件
aluminium amalgam T=100 - 130°C;
参考文献
Gerhardt,W.; Kucharski,S.
Journal fuer Praktische Chemie (Leipzig), 1977 , vol. 319, p. 705 - 712
反应条件
T=140°C; nach dem Erkalten mit HCl-Gas saettigt und dann wieder auf 100grad erhitzt;
参考文献
Lourenco
Annales de Chimie (Cachan, France), 1863 , vol. <3>67, p. 272
参考文献
Wurtz
Annales de Chimie (Cachan, France), 1863 , vol. <3> 69, p. 321
Justus Liebigs Annalen der Chemie, 1862 , vol. 122, p. 354
反应条件
T=150°C; 5 h; dependence of the products of ECH decomposition on temperature in sealed tube at 115, 130, 140, 150, 160 deg C; Product distributionKineticsRate constant;
参考文献
Zil'berman; Kolesnikov; Danov; Efremov; Pantina
Journal of applied chemistry of the USSR, 1985 , vol. 58, # 11 pt 2 p. 2344 - 2347
参考文献
Fourneau; Ribas
Bulletin de la Societe Chimique de France, 1927 , vol. <4> 41, p. 1056
参考文献
Fourneau; Ribas
Bulletin de la Societe Chimique de France, 1927 , vol. <4> 41, p. 1056
反应条件
sodium hydride in N,N-dimethyl-formamide T=20°C; Etherification;
参考文献
Chemistry - A European Journal, , vol. 6, # 1 p. 111 - 122
反应条件
pyridine T=0 - 20°C; Tosylation; 18 h;
参考文献
Christensen; Bryce; Becher
Synthesis, 2000 , # 12 p. 1695 - 1704
反应条件
1: 55 percent / Na2CO3 / 36 h / 110 °C 2: 49 percent Spectr. / toluenesulphonyl chloride, NaOH / dioxane / 5 h / 60 °C / variation of base View Scheme
参考文献
Maeda, Hirokazu; Furuyoshi, Shigeo; Nakatsuji, Yohji; Okahara, Mitsuo
Tetrahedron, 1982 , vol. 38, # 22 p. 3359 - 3362
反应条件
1: 78 percent / sodium / ethanol / Heating 2: aq. NaOH, tetrabutylammonium hydrogensulfate / CH2Cl2 / 72 h / 65 °C 3: 77 percent / liq. NH3, sodium / tetrahydrofuran / 1.) -78 deg C, 1 h, 2.) reflux, 45 min 4: 51 percent / 10-camphorsulfonic acid / methanol View Scheme
参考文献
Boden, Neville; Bushby, Richard J.; Clarkson, Steven; Evans, Stephen D.; Knowles, Peter F.; Marsh, Andrew
Tetrahedron, 1997 , vol. 53, # 31 p. 10939 - 10952
