5,10,15,20-tetrakis-pentafluorophenyl-21H,23H-porphyrin iron(III) chloride; iodosylbenzene in dichloromethane 3 h; Ambient temperaturestudy of C-H and/or C-C bond cleavage on oxidation of alcohol; Product distributionMechanism;
5,10,15,20-tetrakis-pentafluorophenyl-21H,23H-porphyrin iron(III) chloride; iodosylbenzene in dichloromethane 3 h; Ambient temperaturestudy of C-H and/or C-C bond cleavage on oxidation of alcohol; Product distributionMechanism;
C3H8 bulk gas; oxygen
T=37.5°C; Irradiationdifferent substrate, bulk gas and methanol partial pressures and in the given case: in the presence of 4 Torr NMe3 partial pressure; Product distribution;
参考文献
Fornarini, Simonetta; Sparapani, Cinzia; Speranza, Maurizio
Journal of the American Chemical Society, 1988 , vol. 110, # 1 p. 34 - 41