1-(2-乙烯基苯基)-乙酮合成路线 （共 16 条）
反应条件
1: 78 percent / pyridine / Ambient temperature
2: 90 percent / LiCl / Pd2dba3, tri(2-furyl)phosphine / various solvent(s) / 2 h / Ambient temperature
View Scheme
参考文献
Farina, Vittorio; Baker, Stephen R.; Benigni, Daniel A.; Hauck, Sheila I.; Sapino, Chester
Journal of Organic Chemistry, 1990 , vol. 55, # 23 p. 5833 - 5847
参考文献
Gensler et al.
Journal of the American Chemical Society, 1956 , vol. 78, p. 1713,1716
反应条件
tripotassium phosphate monohydrate; Pd/SiO2 in Trimethylene glycol
T=100°C; 4 h;
参考文献
Joucla, Lionel; Cusati, Giuseppe; Pinel, Catherine; Djakovitch, Laurent
Advanced Synthesis and Catalysis, 2010 , vol. 352, # 11-12 p. 1993 - 2001
反应条件
1: bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine / tetrahydrofuran / 12.5 h / 0 °C / |Inert atmosphere; |Reflux
2: potassium carbonate / methanol / 0.5 h / 20 °C / |Inert atmosphere
3: PPh3 gold(I) chloro complex; silver hexafluoroantimonate / methanol / 20 °C / |Inert atmosphere
View Scheme
参考文献
Garcia-Rubin, Silvia; Gonzalez-Rodriguez, Carlos; Garcia-Yebra, Cristina; Varela, Jesus A.; Esteruelas, Miguel A.; Saa, Carlos
Angewandte Chemie - International Edition, 2014 , vol. 53, # 7 p. 1841 - 1844
Angew. Chem., 2014 , vol. 53-126, # 7 p. 1872 - 1875
反应条件
1: potassium carbonate / methanol / 0.5 h / 20 °C / |Inert atmosphere
2: PPh3 gold(I) chloro complex; silver hexafluoroantimonate / methanol / 20 °C / |Inert atmosphere
View Scheme
参考文献
Garcia-Rubin, Silvia; Gonzalez-Rodriguez, Carlos; Garcia-Yebra, Cristina; Varela, Jesus A.; Esteruelas, Miguel A.; Saa, Carlos
Angewandte Chemie - International Edition, 2014 , vol. 53, # 7 p. 1841 - 1844
Angew. Chem., 2014 , vol. 53-126, # 7 p. 1872 - 1875
反应条件
tripotassium phosphate monohydrate; Pd/SiO2 in 1-methyl-pyrrolidin-2-one
4 h; Sealed tubeHeating;
参考文献
Joucla, Lionel; Cusati, Giuseppe; Pinel, Catherine; Djakovitch, Laurent
Advanced Synthesis and Catalysis, 2010 , vol. 352, # 11-12 p. 1993 - 2001
