1: 20 percent / acetyl nitrate / 1.5 h / -30 °C 2: 92 percent / 2.5percent NaOH / dioxane / 0.5 h / Ambient temperature 3: 92 percent / SOCl2 / 3 h / Heating 4: 63 percent / ammonia / diethyl ether; pyridine / 6 h / Ambient temperature View Scheme

sodium hydroxide in ethanol; water 3 h; Heating / reflux;

hydrogenchloride

methanol; sodium methylate

AcONO2 T=-30°C; 1.5 h;

1: 40.9 percent / acetyl nitrate / 1.5 h / -30 °C 2: 85 percent / pyridine / 12 h / Ambient temperature; benzene, reflux, 72 h View Scheme

1: 20 percent / acetyl nitrate / 1.5 h / -30 °C 2: 92 percent / 2.5percent NaOH / dioxane / 0.5 h / Ambient temperature View Scheme