3-(甲硫基)-2-甲基丙烯合成路线 (共 4 条)
反应条件
hydrogenchloride; 1,1,2,2-tetramethylethylene; 3-chloro-benzenecarboperoxoic acid
1.) dichloromethane, 25 deg C, 30 min; Multistep reaction. Further byproducts given. Title compound not separated from byproducts;
参考文献
Schmid, George H.; Strukelj, Mark; Dalipi, Snezana; Ryan, M.Dominic
Journal of Organic Chemistry, 1987 , vol. 52, # 12 p. 2403 - 2407
反应条件
tetrabutyl ammonium fluoride in tetrahydrofuran
3 h; Ambient temperature;
参考文献
Hendrickson, James B.; Boudreaux, Gerald J.; Palumbo, Paul S.
Journal of the American Chemical Society, 1986 , vol. 108, # 9 p. 2358 - 2366
参考文献
Barnard; Fabian; Koch
Journal of the Chemical Society, 1949 , p. 2442,2443
反应条件
potassium tert-butylate in dimethyl sulfoxide
T=25.9 - 119.9°C; ΔG, ΔH, ΔS, stabilization effects of thio groups; Equilibrium constantThermodynamic data;
参考文献
Kimmelma, Reijo
Acta Chemica Scandinavica, Series B: Organic Chemistry and Biochemistry, 1988 , vol. 42, # 8 p. 550 - 555