5,5'-二氨基-2,2'-联吡啶合成路线 （共 5 条）
反应条件
triphenylphosphine; nickel dichloride; zinc in N,N-dimethyl-formamide
T=50°C; coupling; 4 h;
参考文献
Janiak, Christoph; Deblon, Stephan; Wu, He-Ping; Kolm, Mario J.; Kluefers, Peter; Piotrowski, Holger; Mayer, Peter
European Journal of Inorganic Chemistry, 1999 , # 9 p. 1507 - 1521
反应条件
hydrazine hydrate; palladium on activated charcoal in ethanol
16 h; Heating;
参考文献
Asselin, Catherine M.; Fraser, Greig C.; Hall Jr.; Lindsell, W. Edward; Padias, Anne B.; Preston, Peter N.
Journal of the Chemical Society - Dalton Transactions, 1997 , # 20 p. 3765 - 3771
反应条件
sodium hydroxide in ethanol; water
Hydrolysis; 24 h; Heating;
参考文献
Janiak, Christoph; Deblon, Stephan; Wu, He-Ping; Kolm, Mario J.; Kluefers, Peter; Piotrowski, Holger; Mayer, Peter
European Journal of Inorganic Chemistry, 1999 , # 9 p. 1507 - 1521
反应条件
hydroxylamine hydrochloride; triethylamine in ethanol; water
20 h; Reflux;
参考文献
Graffion, Julien; Cattoen, Xavier; Wong Chi Man, Michel; Fernandes, Vasco R.; Andre, Paulo S.; Ferreira, Rute A. S.; Carlos, Luis D.
Chemistry of Materials, 2011 , vol. 23, # 21 p. 4773 - 4782
反应条件
1: 92 percent / SnCl2(H2O)2; HCl
2: 60 percent / NiCl2*6H2O; PPh3; Zn / dimethylformamide / 4 h / 50 °C
View Scheme
参考文献
Janiak, Christoph; Deblon, Stephan; Wu, He-Ping
Synthetic Communications, 1999 , vol. 29, # 19 p. 3341 - 3352
