1: With [RhCl(η2:η2-cycloocta-1,5-diene)]2; NAF in 1,4-dioxane
T=20°C; 0.5 h; Inert atmosphere;
2: With water in tetrahydrofuran; 1,4-dioxane
T=100°C; 26 h; Inert atmosphereSealed tube;
参考文献
Noel, Timothy; Goek, Yasar; Eycken, Johan Van der
Tetrahedron Asymmetry, 2010 , vol. 21, # 5 p. 540 - 543
tetraethylammonium bromide in acetonitrile
T=20 - 25°C; graphite cathode, cathodic reduction, -1.45 V (reference GKE); Title compound not separated from byproducts;
(S,S)-Bn-nbd; tetrakis-(ethylene)-μ,μ'-dichlorodirhodium(I); water in toluene
T=50°C; 48 h; Inert atmosphereSealed tube; optical yield given as percent ee;
参考文献
Noel, Timothy; Goek, Yasar; Eycken, Johan Van der
Tetrahedron Asymmetry, 2010 , vol. 21, # 5 p. 540 - 543
tetraethylammonium bromide; water in acetonitrile
Hg-cathode, cathodic reduction, -1.3 V (reference SCE); Title compound not separated from byproducts;
