(2R,3S,4R,5S,6S)-2-(乙酰氧基甲基)-6-氰基四氢-2H-吡喃-3,4,5-三基三乙酸酯合成路线 (共 24 条)
反应条件
1) 80 deg C, 20 min then quickly to RT, 2) CH3NO2, 48 h, RT; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Myers; Lee
Carbohydrate research, 1986 , vol. 154, p. 145 - 163
反应条件
in nitromethane
48 h; Ambient temperature;
参考文献
Myers; Lee
Carbohydrate research, 1984 , vol. 132, # 1 p. 61 - 82
反应条件
2,2'-azo-bisisobutyronitrile; tri-n-butyl-tin hydride in benzene
0.25 h; Heating; Yield given. Yields of byproduct given;
参考文献
Somsak, Laszlo; Batta, Gyula; Farkas, Istvan
Tetrahedron Letters, 1986 , vol. 27, # 48 p. 5877 - 5880
反应条件
acetic acid
Ambient temperatureother solvent: benzene, AcOH/water; other temperature: reflux; other additive: pyridine, triethylamine; Product distribution;
参考文献
Somsak, Laszlo; Bajza, Istvan; Batta, Gyula
Liebigs Annalen der Chemie, 1990 , # 12 p. 1265 - 1268