二氯(p-甲基异丙苯)钌(II) 二聚体合成路线 （共 9 条）
反应条件
in N,N-dimethyl-formamide other Radiation; subjected to 300-W microwave irradn. at 250°C for 5 min; cooled, pptd. (CH2Cl2/Et2O), recrystd.;
参考文献
Journal of the American Chemical Society, , vol. 128, # 1 p. 46 - 47
参考文献
Pure and Applied Chemistry, , vol. 62, p. 1135 - 1138
参考文献
Takaya, Hidemasa; Ohta, Tetsuo; Mashima, Kazushi; Noyori, Ryoji
Pure and Applied Chemistry, 1990 , vol. 62, p. 1135 - 1138
反应条件
triethylamine in isopropyl alcohol 1 h; Heating / reflux;
参考文献
MERCK FROSST CANADA LTD.
Patent: WO2007/14454 A1, 2007 ;
Location in patent: Page/Page column 17 ;
WO 2007/014454 A1
反应条件
in chloroform Irradiation (UV/VIS); a soln. of the educt in CHCl3 was irradiated at 10°C for 48 h with a 150 W medium pressure Hg lamp;; after filtn. the crystals were dried in vac.; elem. anal.;;
参考文献
Goerissen, Ralf; Koelle, Ulrich; Spaniol, Thomas P.
Polyhedron, 1992 , vol. 11, p. 2317 - 2320
反应条件
1: (S)-(−)-SEGPHOS; [Ru2(p-PriC6H4Me)2(μ-Cl)Cl]2 in methanol; toluene
T=50°C; 1 h;
2: sodium acetate in methanol; toluene
T=50°C; 2 h;
参考文献
TAKASAGO INTERNATIONAL CORPORATION
Patent: US2010/76210 A1, 2010 ;
Location in patent: Page/Page column 7 ;
反应条件
in not given
N2, Ru compd. trated with 2 equiv. of phosphine according to A. Demonceau, Macromolecules, 1997, 30, 3127-3136;
参考文献
Buchmeiser, Michael R.; Wang, Dongren; Zhang, Yan; Naumov, Sergej; Wurst, Klaus
European Journal of Inorganic Chemistry, 2007 , # 25 p. 3988 - 4000
反应条件
in toluene
(Ar); at 70°C;
参考文献
Borguet, Yannick; Sauvage, Xavier; Zaragoza, Guillermo; Demonceau, Albert; Delaude, Lionel
Organometallics, 2010 , vol. 29, # 24 p. 6675 - 6686
反应条件
1: (S)-(−)-DM-SEGPHOS; [Ru2(p-PriC6H4Me)2(μ-Cl)Cl]2 in ethanol; toluene
T=45°C; 1 h;
2: sodium acetate in ethanol; toluene
T=45°C; 3 h;
参考文献
TAKASAGO INTERNATIONAL CORPORATION
Patent: US2010/76210 A1, 2010 ;
Location in patent: Page/Page column 7 ;
