in tetrahydrofuran; dichloromethane addn. of a soln. of Co-complex in THF to a soln. of Mn-compd. in THF/CH2Cl2 under N2, stirring at room temp. for 30 min, colour changes from purple/brown to red/brown; removal of solvent in vacuo, extn. with hexane to yield a yellow fraction, extn. of hexane insoluble solid with CH2Cl2 give a brown fraction;
参考文献
Duffy, D. Neil; Kassis, Maram M.; Rae, A. David
Journal of Organometallic Chemistry, 1993 , vol. 460, # 1 p. 97 - 104
in acetonitrile
Kinetics; react. of the metal carbonyl anion (0.001 M) with an excess of the Co(III) complex (0.10-0.30 M) at 25°C in CH3CN; detn. by decrease of the IR intensity of the metal carbonyl anion;
参考文献
Corraine, M. Shauna; Lai, C. K.; Zhen, Yueqian; Churchill, Melvyn Rowen; Buttrey, Lisa A.; et al.
Organometallics, 1992 , vol. 11, p. 35 - 40
in acetonitrile
Kinetics; react. of the metal carbonyl anion (0.001 M) with an excess of the Co(III) complex (0.10-0.30 M) at 25°C in CH3CN; detn. by decrease of the IR intensity of the metal carbonyl anion;
参考文献
Corraine, M. Shauna; Lai, C. K.; Zhen, Yueqian; Churchill, Melvyn Rowen; Buttrey, Lisa A.; et al.
Organometallics, 1992 , vol. 11, p. 35 - 40
