zinc cyanide in N,N-dimethyl-formamide T=110°C; 3 h; Yield given;

1: 20 percent NaCl-solution / pH </= 1 2: NaHCO3 / H2O / 8 h / 15 - 25 °C 3: 1) NaNO2, conc. H2SO4; 2) amidosulfuric acid, HCl / 1) 2 h, r.t.; 2) water, 6 h View Scheme

1: HCl / H2O / 8 h / pH = 1,5-3,5 2: 20 percent NaCl-solution / pH </= 1 3: NaHCO3 / H2O / 8 h / 15 - 25 °C 4: 1) NaNO2, conc. H2SO4; 2) amidosulfuric acid, HCl / 1) 2 h, r.t.; 2) water, 6 h View Scheme

1: NaHCO3 / H2O / 8 h / 15 - 25 °C 2: 1) NaNO2, conc. H2SO4; 2) amidosulfuric acid, HCl / 1) 2 h, r.t.; 2) water, 6 h View Scheme

hydrogenchloride; sulfuric acid; aminosulfonic acid; sodium nitrite 1) 2 h, r.t.; 2) water, 6 h; Yield given. Multistep reaction;