反应条件
in tetrahydrofuran; water; pentane
under N2, CoBr2*DME, LiCp, CoCp2 and COD mixed in THF in molar ratio of2/2.06/0.5/1.16, warmed to room temp. during 3 h, evapd., pentane ext. passed through Al2O3/4percent H2O and CuCl powder; concd., cooled to -80°C, CpCoCOD filtered off; CuCl washed with water, CoCp2(1+) pptd. with BPh4(1-) from aq. soln., filtered off; pentane-insol. residue treated with water, Co and CoO mixt. filtered, Co(2+) determined complexometrically;
参考文献
Koelle, U.; Sistig, F.; Gersdorf, J.
Journal of Organometallic Chemistry, 1982 , vol. 233, # 2 p. 253 - 258
